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Synthesis of longer chain tertiary alcohols
@Nicodem:

Thanks. The de-esterification of terpineol acetate won't be easy either though, I imagi ...
12-1-2016 at 09:51
by: blogfast25
Hydrochlorination of alk-1-ene?
[rquote=434983&tid=64979&author=Nicodem]
Yes, it qualifies very well for an electrophilic a ...
12-1-2016 at 09:38
by: blogfast25
Using a small deep fryer as an oil bath
I use one too. No problems at all.
12-1-2016 at 07:47
by: blogfast25
Synthesis of longer chain tertiary alcohols
[rquote=434962&tid=15171&author=aga]OK. So i need to have a good long stare at dissolution i ...
12-1-2016 at 07:02
by: blogfast25
Hydrochlorination of alk-1-ene?
[rquote=434921&tid=64979&author=byko3y]I've had such experience. I've used silica gel as a c ...
11-1-2016 at 15:38
by: blogfast25
Synthesis of longer chain tertiary alcohols
[rquote=434919&tid=15171&author=aga]
[b]I.[/b] If they Dissolve and not simply Mix, Acetone ...
11-1-2016 at 15:24
by: blogfast25
RogueSci
Ok, maybe we should drop this NBK stuff now? I mean, what next on SM, snuff movies?
11-1-2016 at 14:50
by: blogfast25
Equilibrium constant question
[rquote=434897&tid=64986&author=SunriseSunset]Does anyone know a youtube video that shows th ...
11-1-2016 at 14:45
by: blogfast25
Synthesis of longer chain tertiary alcohols
Take HCl as a simpler example (monoprotic). As a strong acid it completely deprotonates:

HCl(aq) ...
11-1-2016 at 14:27
by: blogfast25
Synthesis of longer chain tertiary alcohols
double post eliminated

[Edited on 11-1-2016 by blogfast25]
11-1-2016 at 14:06
by: blogfast25
Hydrochlorination of alk-1-ene?
[rquote=434901&tid=64979&author=Nicodem]The [i]Organic Syntheses[/i] example is a Michael ad ...
11-1-2016 at 13:34
by: blogfast25
Synthesis of longer chain tertiary alcohols
[rquote=434896&tid=15171&author=aga]
[b]I.[/b] The system isn't really uniphasic - if left ...
11-1-2016 at 12:57
by: blogfast25
Notes on acetone as a solvent (here)
The need for a solvent has already been explained in terms of homogeneous catalysis being generally ...
11-1-2016 at 09:25
by: blogfast25
RogueSci
The real danger though is terrorism. The chemistry of these things has been known for a long time, I ...
11-1-2016 at 08:25
by: blogfast25
Making copper salts (especially basic copper carbonate)
[rquote=434091&tid=64890&author=Fulmen]

Edit: This process is also said to produce a unif ...
11-1-2016 at 03:45
by: blogfast25
RogueSci
[rquote=434871&tid=63069&author=woelen]I can imagine that these people really try to do thes ...
11-1-2016 at 03:22
by: blogfast25
Make Potassium (from versuchschemie.de)
[rquote=434858&tid=14970&author=NeonPulse]I had today only received my 99.9% ingots of Mg to ...
11-1-2016 at 03:19
by: blogfast25
Equilibrium constant question
[rquote=434868&tid=64986&author=SunriseSunset]So my book has an equilibrium constant of = 1. ...
11-1-2016 at 02:43
by: blogfast25
Make Potassium (from versuchschemie.de)
[rquote=434832&tid=14970&author=Etaoin Shrdlu]That one looks nice too.[/rquote]

I'm afrai ...
10-1-2016 at 18:33
by: blogfast25
Hydrochlorination of alk-1-ene?
[rquote=434834&tid=64979&author=Magpie]I heated a mixture of 95% NaHSO4 and NaCl. The mix w ...
10-1-2016 at 18:04
by: blogfast25
Synthesis of longer chain tertiary alcohols
The more I look at that paper (TCA, 2013) the less I like it. There are real ABSURDITIES in it.

...
10-1-2016 at 17:42
by: blogfast25
Make Potassium (from versuchschemie.de)
[rquote=434828&tid=14970&author=Etaoin Shrdlu]Ran across this while cleaning and thought som ...
10-1-2016 at 17:09
by: blogfast25
Synthesis of longer chain tertiary alcohols
The abstract of that paper:

[quote]Chloroacetic acid was used as catalyst for the hydration of α ...
10-1-2016 at 16:29
by: blogfast25
Synthesis of longer chain tertiary alcohols
[rquote=434822&tid=15171&author=aga]
TCA as catalyst producing more alpha-terpineol in less ...
10-1-2016 at 15:50
by: blogfast25
Hydrochlorination of alk-1-ene?
[rquote=434820&tid=64979&author=Magpie]You may find this useful:

http://www.sciencemadnes ...
10-1-2016 at 15:31
by: blogfast25
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