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thionyl chloride synthesis
Refer to the Inorg.Syn. procedure for Cl2O prep. and to the Brauer prep (just for the stoichiometry ...
9-2-2009 at 10:12
by: Sauron
thionyl chloride synthesis
Thanks to vovan78 I have the Wurtz paper from Annalen 139 (1866( and as expected it is a word for wo ...
9-2-2009 at 04:35
by: Sauron
thionyl chloride synthesis
Thanks, Klute for the fine translation. Formatik and I should both be satified. Gmelin did not err, ...
9-2-2009 at 04:10
by: Sauron
thionyl chloride synthesis
The question is not whether Gmelin explicitly stated that CS2 moderates the reaction. They didn't, a ...
8-2-2009 at 23:31
by: Sauron
thionyl chloride synthesis
It's page 460 not 490.

Wurtz article attached.

Contrary to the Gmelin quote above, this paper ...
8-2-2009 at 10:13
by: Sauron
thionyl chloride synthesis
If this is the paper you are talking about, thanks anyway but I have already requested it.

Synthe ...
8-2-2009 at 08:42
by: Sauron
thionyl chloride synthesis
Very odd. According to Gmelin, the reaction between CS2 and Cl2O is violent/explosive. But it is al ...
8-2-2009 at 04:18
by: Sauron
Tinkery or Science?
There are people on this forum who might fit your first idea and there are others here who come very ...
8-2-2009 at 01:21
by: Sauron
Antimony analog of Paris Green?
I believe Paris Green was copper acetoarsenate. I do not know if Sb forms acetoantimonates.

In ge ...
7-2-2009 at 01:34
by: Sauron
On the subject of ORMUS
I doubt the dinosaur will realize it is dead for some time. Brain is too small and too remote from t ...
6-2-2009 at 10:17
by: Sauron
gas regulator needed for propane tank
Admittedly. Actually that's not precisely a tautology, merely a redundancy. A tautology would be "Al ...
6-2-2009 at 05:19
by: Sauron
On the subject of ORMUS
That is what we scientists call anecdotal, which is a technical term for bullshit.

It is most cer ...
6-2-2009 at 05:13
by: Sauron
On the subject of ORMUS
Oh come ON. This is a SCIENCE forum, cut the magical newage sewage please! Gold is not in PDR. Have ...
6-2-2009 at 04:19
by: Sauron
gas regulator needed for propane tank
Harris makes regulators in that price class but they are gaugeless designs. Gauges cost money.

ht ...
6-2-2009 at 03:42
by: Sauron
On the subject of ORMUS
There's more hard science in GHOSTBUSTERS than in David Hudson's frauds or this thread.

The man i ...
5-2-2009 at 23:42
by: Sauron
On the subject of ORMUS
Wake me up when this thread is over.
5-2-2009 at 16:12
by: Sauron
CODESSA, AMPAC, DRAGON
Ampac is very little different from MOPAC as both originated as the same project from Michael Dewar' ...
5-2-2009 at 15:30
by: Sauron
thionyl chloride synthesis
It does appear to be faster and easier than direct chlorination of m-xylene. The third chlorine on e ...
5-2-2009 at 10:17
by: Sauron
thionyl chloride synthesis
The vapor pressure of Cl2O over CCl4 solutions, at least dilute ones, obeys Henry's Law.

1800-so ...
5-2-2009 at 09:29
by: Sauron
gas regulator needed for propane tank
After avoiding gas reulators for years due to looking at needless Aldrich markup. I have been very h ...
5-2-2009 at 08:50
by: Sauron
thionyl chloride synthesis
Ah. You are suggesting to reverse the order of addition. The preparation of Cl2O in CCl4 usually pas ...
5-2-2009 at 08:25
by: Sauron
thionyl chloride synthesis
Yes, but the chief virtue of thionyl chloride as a reagent for acyl chlorides is that it only has ga ...
5-2-2009 at 02:44
by: Sauron
gas regulator needed for propane tank
Harris is manufactured in your state so ought to have good distribution there and their brass butane ...
4-2-2009 at 22:53
by: Sauron
thionyl chloride synthesis
S.C., don't get your knickers in a twist. You'll do yourself an injury.

Forget the prep of neat C ...
4-2-2009 at 21:50
by: Sauron
thionyl chloride synthesis
Here's Chemical Review monograph on the chemistry of Cl2O from the 1970s. Cl2O is of industrial and ...
4-2-2009 at 09:48
by: Sauron
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