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Gallium in an Al/Hg reduction
Yes, there is a paper on this effect already. I don't have it handy, but it will work for reductions ...
24-3-2008 at 11:21
by: Fleaker
Sulfur trioxide from sodium hydrogen sulfate
Excellent work!! This is a cheap and effective synthesis for SO3, one I will probably do at home as ...
24-3-2008 at 10:35
by: Fleaker
I Have Ethyl Acetate and KI
I'd probably buy various things. I'd rather have NaI than KI...more bang for your buck iodine conten ...
24-3-2008 at 10:12
by: Fleaker
Synthesis of Sulfur Trioxide and Oleum: The persulfate method
No so difficult at all vulture; heat will drive it out, and so will vacuum.
21-3-2008 at 14:50
by: Fleaker
Write-up on synthesis of K3CrO8, a very energetic peroxochromate
While len has valid concerns, I am with Woelen and Chemoleo: small time exposures really don't add u ...
19-3-2008 at 11:22
by: Fleaker
Home Chemistry Society
MagicJigPipe,

I don't think we should exclude professional chemists! Don't forget that quite a fe ...
18-3-2008 at 14:17
by: Fleaker
Adios
What a pity. This is becoming intolerable.
12-3-2008 at 09:44
by: Fleaker
WANTED: Barium and Strontium metal
I could order a kilogram of each from Alfa, but there would have to be enough interest from others o ...
12-3-2008 at 09:35
by: Fleaker
A attempt at Halfapint's dimethylsulfate synthesis..
I tried this reaction again last night on a larger scale using 50 mL of MeOH and excess oleum.
The ...
11-3-2008 at 04:41
by: Fleaker
www.totallysynthetic.com
Nicodem, your posts are hilarious!

Drunkguy, thanks for the link to totalsynthesis, I hadn't seen ...
10-3-2008 at 16:07
by: Fleaker
Are you a real mad scientist?
While I think it would be nice to live longer, I would far rather live happily.


As for what bfe ...
8-3-2008 at 19:15
by: Fleaker
Testing Ar-flushed apparatus for oxygen
Argon is cheap enough, 20 dollars for 148 cubic feet of it at the welding store. The tank is what is ...
8-3-2008 at 11:32
by: Fleaker
Testing Ar-flushed apparatus for oxygen
Couldn't you just vacuum distill it and save gas?
7-3-2008 at 18:30
by: Fleaker
bromine
You'll have proof of Br2 being easy to isolate quite soon. There are ample examples already on the f ...
7-3-2008 at 12:17
by: Fleaker
Synthesis of 3-(p-Hydroxyphenyl)-2-Butanone "raspberry ketone"
Very nice post Klute.

Many catalytic converters contain rhodium along with other amounts. I doubt ...
6-3-2008 at 15:00
by: Fleaker
Platinum-Tungsten Separation and Other Mystery Metals
Iridium is much rarer than platinum, however, it is much less useful and much more difficult to proc ...
6-3-2008 at 06:15
by: Fleaker
Ruthenium metal
Well that would be 100g of PtRu on what I think is some sort of trade name for carbon black.

If i ...
6-3-2008 at 06:06
by: Fleaker
Platinum-Tungsten Separation and Other Mystery Metals
Likewise on the iridium.


I'm seconding the use of peroxide.

Reason other acids (save HF) don ...
5-3-2008 at 17:09
by: Fleaker
Ruthenium metal
I have acquired some ruthenium metal. It is catalytic grade and is suitable for many experiments, in ...
5-3-2008 at 10:50
by: Fleaker
Platinum Anode
Mind you it wasn't his 300 dollar a gallon plating bath, and that was back in December, about 600 do ...
2-3-2008 at 08:38
by: Fleaker
Platinum Anode
What of it? Should we discuss some platinum anodes?

I can post a picture of some commonly seen pl ...
1-3-2008 at 19:46
by: Fleaker
Butyl Diglyme solvent extraction process.
http://www.goldrefiningforum.com has pictures of the process and first hand experience posted up.

...
29-2-2008 at 09:57
by: Fleaker
Compressed Gases on the Cheap
What is wrong with renting cylinders? Usually one time deposit that you get back, and then monthly f ...
28-2-2008 at 18:28
by: Fleaker
Acetic anhydride preparation
:-) By some of us I did not mean me, I have several that I can use. Soon I'll have a very nice one a ...
27-2-2008 at 14:13
by: Fleaker
Acetic anhydride preparation
Hm, so to make this useful one would need a good source of dry chlorine, a tube furnace, and some si ...
27-2-2008 at 10:50
by: Fleaker
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