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NOCl as chlorinating/nitrating agent?
For ethers R-O-R,
HNO3 + 3 HCl= Cl2 + 2 H2O + NOCl
NOCl + R-O-R = R-NO2 + R-Cl
Cl2 + 2R-NO2 = 2 ... |
20-9-2009 at 11:49
by: ketel-one |
The short questions thread (2)
Lol, good point. I Must've had some unreacted alcohol.
Does anyone know... if you try to halogena ... |
19-9-2009 at 21:30
by: ketel-one |
toluene --> benzaldehyde
Doesn't styrene undergo alkene addition to form benzyl chloride? It would be awsome if styrene can b ... |
19-9-2009 at 01:25
by: ketel-one |
The short questions thread (2)
Alkylation reactions have to be performed in nonpolar solvent right? A 40% aqueous alkyl halide woul ... |
18-9-2009 at 23:55
by: ketel-one |
The short questions thread (2)
Many thanks Chaos, that explains everything.
Oh and that CH2CH2 should have been CH3CH3 obviously ... |
18-9-2009 at 20:23
by: ketel-one |
The short questions thread (2)
^interesting question. The way I imagine it is that the AcO* radical would do a hunsdiecker type thi ... |
18-9-2009 at 19:15
by: ketel-one |
toluene --> benzaldehyde
Right, here's the patent referred to [URL]http://www.freepatentsonline.com/1280612.pdf[/URL] I don't ... |
15-9-2009 at 22:48
by: ketel-one |
Unreactive properties of KClO4?
[rquote=162248&tid=12809&author=woelen] That demo is nice for showing how bleach can oxidize ... |
15-9-2009 at 22:08
by: ketel-one |
toluene --> benzaldehyde
Ive never tried it, but the stuff on this site should be pretty accurate. [URL]http://www.erowid.org ... |
15-9-2009 at 21:58
by: ketel-one |
toluene --> benzaldehyde
toluene + Ca(OCl)2 @105C with no other reagents should make benzyl chloride... |
15-9-2009 at 20:43
by: ketel-one |
The short questions thread (2)
I was pleasantly surprised today. I put some vodka in a glass in the freezer. I was expecting it not ... |
14-9-2009 at 21:45
by: ketel-one |
Acetic anhydride preparation
Ok I see, only compounds that hydrolyze in water would work, dehydration by itself won't. |
13-9-2009 at 17:49
by: ketel-one |
Unreactive properties of KClO4?
Zinc seems nice because it's super obtainable. Just broke into couple alkaline batteries, trying to ... |
13-9-2009 at 17:17
by: ketel-one |
Acetic anhydride preparation
I don't think S2Cl2 will work, it doesn't have S to Cl atoms in right proportion.
I think SO2Cl2 ... |
13-9-2009 at 16:46
by: ketel-one |
The short questions thread (2)
No it's my fault I wasn't completely correct in what I was saying.
I figured it out, it's not th ... |
12-9-2009 at 23:42
by: ketel-one |
The short questions thread (2)
Ammonium, I love you with all my heart. But I am dumbfounded by your responses.
[quote]Why the s ... |
12-9-2009 at 23:10
by: ketel-one |
The short questions thread (2)
Yes, but look closely at the structure. There's an aromatic pyrrole ring hidden in there.
[IMG]http ... |
12-9-2009 at 22:44
by: ketel-one |
The short questions thread (2)
What is indole? Benzene ring fused to pyrrole ring. Pyrrole is aromatic so doesn't get alkylated obv ... |
12-9-2009 at 21:02
by: ketel-one |
Can diethyl-ether substitute for ethanol?
[rquote=161884&tid=12800&author=DJF90]One good thing you can do with 2-benzyl pyridine is ni ... |
9-9-2009 at 18:17
by: ketel-one |
The short questions thread (2)
[rquote=161876&tid=12054&author=Klute]Certainly not something for newbees or even intermedia ... |
9-9-2009 at 11:32
by: ketel-one |
Acetyl Chloride Megathread
Right, right don't know what I was thinking, I guess PCl3 is the best bet then... I just noticed in ... |
9-9-2009 at 06:03
by: ketel-one |
Can diethyl-ether substitute for ethanol?
You're right John, the synthesis I was originally looking at says to use "H2, Pt, CH3CH2OH"
But ... |
8-9-2009 at 22:17
by: ketel-one |
The short questions thread (2)
Oh right I just remembered a good way to get sulfur... Lots of matches in HCl, i believe last time I ... |
8-9-2009 at 20:55
by: ketel-one |
Acetyl Chloride Megathread
I suppose phosgene can make AcCl... And I suppose it can be made from chloroform... And I suppose ch ... |
8-9-2009 at 20:52
by: ketel-one |
Acetyl Chloride Megathread
I'm just thinking there's got to be some other chlorinating agents, something besides phosphorous th ... |
8-9-2009 at 19:49
by: ketel-one |
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