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Reaction mechanism? Anodic oxidation of chloride
This reaction:

6ClO(-) + 3H2O - 6e --> 2ClO3(-) + 4Cl(-) + 6H(+) + 3/2O2 (A)

looks not ...
25-9-2010 at 06:30
by: kmno4
What is 1,3-diisonitrosoacetone guanidinium salt
[rquote=187575&tid=14466&author=Anders2]diisonitrosoacetone can condense with hydroxylamine ...
17-9-2010 at 15:03
by: kmno4
Anode for chloride electrolysis ?
[rquote=187412&tid=14479&author=Xenoid]Please do a little research before making such a sill ...
17-9-2010 at 07:14
by: kmno4
Hydrochloric acid hydrogen peroxide mix
Something to read:
THE PROPERTIES OF PURE HYDROGEN PEROXIDE. IV. ACTION OF THE HALOGENS AND HALOGEN ...
15-9-2010 at 22:05
by: kmno4
Hydrochloric acid hydrogen peroxide mix
This mixture is not stable and gives off Cl2 gas, sooner or later but it does.
H2O2/HCl mixture is ...
15-9-2010 at 14:01
by: kmno4
Toluene and n-butyl acetate azeotrope?
There is something like this: Advances in chemistry no.6 -AZEOTROPIC DATA.
According to it, there i ...
14-9-2010 at 21:52
by: kmno4
H2SO4 by displacement of CuSO4 with H2?
[rquote=186878&tid=14432&author=bluflame]We know that more reactive metals will displace les ...
5-9-2010 at 23:59
by: kmno4
Strange purple compound when oxidizing p-aminophenol
Something to read:
[b]Benzoquinone imines. Part 16. Oxidation of p-aminophenol in aqueous solution
...
29-8-2010 at 06:47
by: kmno4
Strange purple compound when oxidizing p-aminophenol
In experiments with reduction of nitrosophenol I observed the same colors.
When nitrosophenol was r ...
27-8-2010 at 11:58
by: kmno4
Question: preparation of MnO
Nice colour :)
According to "Chemistry of the Elements (2nd Edition)" by Greenwood, N.N.; Earnshaw, ...
19-8-2010 at 12:54
by: kmno4
Acids/bases: heats of neutralisation
[rquote=185050&tid=14247&author=blogfast25][rquote=185046&tid=14247&author=kmno4]
6 ...
17-8-2010 at 09:16
by: kmno4
Question: preparation of MnO
To test new H2 generator I made experiment with MnO2 reduction.
Starting material: MnO2 prepared fr ...
16-8-2010 at 12:56
by: kmno4
help with mechanisms
At first - I am the last one who will propose any mechanisms just out of my head.
"While I agree wi ...
14-8-2010 at 12:22
by: kmno4
Acids/bases: heats of neutralisation
Yes - the book I mentioned ( translated) is “Lehrbuch der Elektrochemie” by G. Kortüm from ~196 ...
12-8-2010 at 08:36
by: kmno4
Acids/bases: heats of neutralisation
Value ΔG = 6,49 kcal/mol strictly corresponds to thermodynamic constant [b]K[/b]=1,754x10& ...
12-8-2010 at 06:05
by: kmno4
Acids/bases: heats of neutralisation
Your value of heat of neutralisation of CH3COOH with NaOH solution is in error.
I do not know what, ...
11-8-2010 at 09:13
by: kmno4
Preparation of anhydrous AlCl3 in DCM - photos
I have just done experiment with amalgamated Al and DCM.
I was interested if any reaction occurs.
...
19-7-2010 at 13:56
by: kmno4
H+Sponge/easy12-ring-resonance synthesis idea
According to Hückel's rule your compound cannot be benzene-like aromatic molecule and it remains st ...
18-7-2010 at 13:44
by: kmno4
Preparation of anhydrous AlCl3 in DCM - photos
[rquote=182570&tid=14111&author=Sedit]....there are a gazzlion writeups spaking of the solen ...
17-7-2010 at 08:52
by: kmno4
Preparation of anhydrous AlCl3 in DCM - photos
Your posts are too complicated for me, too much reading about unimportant and off-topic details (sor ...
16-7-2010 at 10:08
by: kmno4
Yellow impurity in nitrobenzene?
The first fime I nitrated benzene I kept temperature max 60 C, adding benzene to acids mixture. Yiel ...
14-7-2010 at 10:54
by: kmno4
The trouble with neodymium...
[rquote=182217&tid=14145&author=blogfast25]

I don't believe this magnet contained any app ...
13-7-2010 at 00:34
by: kmno4
The trouble with neodymium...
To check if your magnet contain only Nd, not Nd+Pr mixture you should take a sample and precipitate ...
12-7-2010 at 02:04
by: kmno4
Question: preparation of MnO
[rquote=181771&tid=14106&author=Bezaleel]kmno4, how did you build your hydrogen generator?
...
8-7-2010 at 07:36
by: kmno4
Question: preparation of MnO
[rquote=181598&tid=14106&author=Bezaleel]
Heating in a stream of hydrogen! Anyone who ever ...
4-7-2010 at 13:28
by: kmno4
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