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Methylation of phenols with Methyl Nitrate
Your definition is incomplete. It does not account for methyl halides such as MeBr and MeI which sur ...
21-3-2009 at 13:59
by: Sauron
Methylation of phenols with Methyl Nitrate
I would be surprised if it were NOT carcinogenic. All methylating agents are AFAIK. Higher alkylatin ...
21-3-2009 at 12:55
by: Sauron
Methylation of phenols with Methyl Nitrate
We already know what to expect from dimethyl sulfate and iodomethane. While I have no phobia of them ...
21-3-2009 at 11:30
by: Sauron
Methylation of phenols with Methyl Nitrate
I wonder if MeONO2 will react with KSCN to give MeSCN and KNO3?

Usually MeI or DMS are used.
21-3-2009 at 10:33
by: Sauron
Cyanuric Triazide
So the yield is trivial and the purification problematic. Oh joy.

These problems do not apply to ...
20-3-2009 at 23:06
by: Sauron
Cyanuric Triazide
Take up garage chemist's offer, I have experience with machine translation of OCR and it varies from ...
20-3-2009 at 10:53
by: Sauron
Cyanuric Triazide
This should be no surprise since cyanuric chloride os also produced by chlorinating methyl thiocyana ...
20-3-2009 at 08:44
by: Sauron
New FTP
I can introduce you to the guy who takes care of my hosting, and I can tell him to treat you like he ...
20-3-2009 at 05:20
by: Sauron
PEA and mek -> NPP?
I am very preoccupied with downloading 110 years of JACS volumes at present and after that I have a ...
19-3-2009 at 00:18
by: Sauron
I need help understanding isomers.
Firstly the sort of isomer that you are referring to is a structural isomer. As you will see there a ...
18-3-2009 at 03:23
by: Sauron
simple distillation problem
Lambda is right.

A SIMPLE distillation is one with NO column interposed between flask and condens ...
16-3-2009 at 23:22
by: Sauron
PEA and mek -> NPP?
Oh, I absolutely agree about conducter and BobHawser and their ilk, I would think I make that perfec ...
16-3-2009 at 03:39
by: Sauron
PEA and mek -> NPP?
The decarboxylation of lysine to produce cadaverine was described in Ber. 18, 2956 (1885), and I thi ...
16-3-2009 at 02:48
by: Sauron
PEA and mek -> NPP?
Sandmeyer, as usual, I couldn't give a damn about what you think is "interesting".

What you chara ...
15-3-2009 at 21:23
by: Sauron
Ideas on forming diethylene glycol
Did I say it wasn't useful?

I said, if you read the reference, that is causes tumors in orally ex ...
15-3-2009 at 17:26
by: Sauron
PEA and mek -> NPP?
It wasn't my stinky corpse juice. That was someone else who wanted to dry-distill it from lysine, se ...
15-3-2009 at 10:31
by: Sauron
PEA and mek -> NPP?
For formation of acetonedicarboxylic acid from oleum, smartass, try my thread on things to do with c ...
15-3-2009 at 09:24
by: Sauron
Ideas on forming diethylene glycol
I do not know. Not that I am aware, at least not readily. But dioxane has that rep, almost as bad as ...
15-3-2009 at 09:05
by: Sauron
Ideas on forming diethylene glycol
It's a serious suspected carcinogen and also a much worse peroxide former than Et2O,

Have a look ...
15-3-2009 at 05:02
by: Sauron
PEA and mek -> NPP?
Got any lit. on that?

Or is this old rhodium stuff?

The dehydration of the triamide, how? P2O ...
15-3-2009 at 02:37
by: Sauron
PEA and mek -> NPP?
Probably because drug cookery is discouraged here, and 4-piperidone has little use other than making ...
15-3-2009 at 00:15
by: Sauron
Allstar Lab?
Fortunately LAH is not the only possible means of effecting the reduction of a dicarboxylic acid to ...
14-3-2009 at 23:25
by: Sauron
cinnamon oil vs. cinnamon aldehyde
Yeah, all that stuff on rhodium archive about eugenol and vanillin as precursors for illegal drugs,. ...
14-3-2009 at 19:17
by: Sauron
Ideas on forming diethylene glycol
BromicAcid, do you really want this clueless fellow to play with p-dioxane? For starters it is nasty ...
14-3-2009 at 18:25
by: Sauron
Synthesis of malonic acid
John, I know quite a number of MDs who did not come from money, were not only children, and if they ...
14-3-2009 at 07:08
by: Sauron
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