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Cl2 + CS2 -> four very useful compounds
Here's a zip file of the two Org.Syn. articles on this C8H8S8 system.

The first starts with CS2 a ...
8-2-2007 at 20:48
by: Sauron
Cl2 + CS2 -> four very useful compounds
I guess we ought to get the CS2-making thread (quite extensive) going again rather than trying to re ...
8-2-2007 at 19:11
by: Sauron
Cl2 + CS2 -> four very useful compounds
@BromicAcid, thanks much. I also suffer from an overabundance of projects and insufficiency of time. ...
8-2-2007 at 18:34
by: Sauron
Cl2 + CS2 -> four very useful compounds
Thiophosgene

C(=S)Cl2

was a failure as a WWI war gas because unlike phosgene it is non-insidio ...
8-2-2007 at 13:10
by: Sauron
Ground glass joints - US to EU ISO adaptors?
Quote:
"Correct me if I am wrong but NIST is a government agency.
Dates from 1901, part of Commer ...
8-2-2007 at 11:48
by: Sauron
Thermate
Just remember it's molten iron we are talking about, 2500 C, 705 Kcal/gram released and the white ho ...
8-2-2007 at 11:39
by: Sauron
Cl2 + CS2 -> four very useful compounds
If the slow trickle of CS2 and slow feed of Cl2 to column bed of GAC does not appeal, the same rxn c ...
8-2-2007 at 11:04
by: Sauron
Cl2 + CS2 -> four very useful compounds
Not that I am aware of, but then how to you lower heat of reaction? Find a catalyst.

I found this ...
8-2-2007 at 10:21
by: Sauron
sodium is expensive
Thanks @fleaker. Very nice.
8-2-2007 at 09:39
by: Sauron
Permanently Plastic Sulfur
@Roscoe, that is quite neat.
8-2-2007 at 09:31
by: Sauron
Cl2 + CS2 -> four very useful compounds
@GC

Calcium carbide becomes incandescent in sulfur vapor at 500 C forming calcium sulfide and car ...
8-2-2007 at 08:56
by: Sauron
Thermate
You will want page T-189 of Volume 9 of PATR 2700

They give only the TH3 composition, but say it ...
8-2-2007 at 02:27
by: Sauron
Cl2 + CS2 -> four very useful compounds
That's odd. After all it clearly does work on an industrial scale and has for hundreds of years. I w ...
8-2-2007 at 02:14
by: Sauron
Thermate
There are at least three standard thermate compositions in US military use, I believe they are desig ...
8-2-2007 at 00:31
by: Sauron
Cl2 + CS2 -> four very useful compounds
Here are two US patents from the 1970s to AKSO and a Synthesis (Thieme) article (in German) by same ...
8-2-2007 at 00:20
by: Sauron
Cl2 + CS2 -> four very useful compounds
This is a very simple and highly productive reaction that directly produces two comounds that are bo ...
7-2-2007 at 23:30
by: Sauron
Separation of Acetone and Nitroethane
OK as it is no longer germaine to anything.
7-2-2007 at 22:32
by: Sauron
Separation of Acetone and Nitroethane
@pantone, it was used by @cyberzed in the post immediately preceding my remark.

I no longer see ...
7-2-2007 at 22:02
by: Sauron
Separation of Acetone and Nitroethane
Is sodium nitrite a problem to get? Not here. I have several Kg on hand of the Ajax product out of A ...
7-2-2007 at 22:00
by: Sauron
Separation of Acetone and Nitroethane
Fractional crystallization ought to work, getting to decent purity would entail several repetitions ...
7-2-2007 at 21:04
by: Sauron
Separation of Acetone and Nitroethane
@cyberzed, kindly tell me what difficult to obtain reagents you are talking about?

n-Propanol?
...
7-2-2007 at 20:04
by: Sauron
Methylphosphonates and derivatives
You like using phosgene better than using AHF?

Anyway AHF is only one method of converting DC to ...
7-2-2007 at 19:41
by: Sauron
sodium is expensive
I bought mine 3-4 years ago along with some Li wire and 250 g of K. At this point I would have to wa ...
7-2-2007 at 10:45
by: Sauron
Ground glass joints - US to EU ISO adaptors?
I am really concerned about Brazilian standards.

ANSI is not a government agency and despite the ...
7-2-2007 at 10:31
by: Sauron
sodium is expensive
Why don't you change the title of thread to "Sodium is Not So Expensive" ?
7-2-2007 at 10:06
by: Sauron
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