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unconventional sodium
In a non-aqueous, non-ionizable solvent nothing else can happen unless there's foreign cations ...
19-11-2003 at 08:01
by: Theoretic
alternative oxidizers for hydrazine production
Hydrazine could be distilled from concentrated solutions of NaOH or CaCl2 or any other dehydrating a ...
19-11-2003 at 07:47
by: Theoretic
Sodium Ethyl Sulfate
"SO3 (by decomposition of CuSO4 or else)"
HUH? It takes a temperature over a thousand deg ...
19-11-2003 at 07:33
by: Theoretic
New sections
I propose that two new sections should be made - one for organic chemistry and one for locked topic ...
18-11-2003 at 08:46
by: Theoretic
alternative oxidizers for hydrazine production
The MSDS for calcium hypochlorite says: "product decomposes at 180 C releasing oxygen gas" ...
18-11-2003 at 08:26
by: Theoretic
Ethylene explorations
""And R+ would combine rapidly and irreversibly with NO2-, right?"
This reaction me ...
18-11-2003 at 05:41
by: Theoretic
lead azide from lead nitrate?
Hmmm... Sodium amide is prepared by reacting sodium oxide with liquid ammonia, but maybe gaseous amm ...
17-11-2003 at 08:44
by: Theoretic
The perfect explosive(s)
OK, in the bin that goes. :(
But what about cyanuric trinitrate - C3N3(NO2)3? Should be preparable ...
17-11-2003 at 08:15
by: Theoretic
Cyanogen nitrite/nitrate
It doesn't seem that ClNO2 can be made by direct chlorination, my book states the opposite. But ...
17-11-2003 at 08:01
by: Theoretic
Sodium Azide
Sodium azide should be synthesizeable like this:
1)2N2H4 + N2O3 => 2HN3 + 4H2O.
2)HN3 + NaOH =& ...
17-11-2003 at 07:48
by: Theoretic
alternative oxidizers for hydrazine production
May I suggest a completely different approach. High-temperature, anhydrous and molten. Specifically, ...
17-11-2003 at 07:38
by: Theoretic
Kolbe reaction
Hmmm... Sounds nice! Under what conditions does this work?
17-11-2003 at 05:56
by: Theoretic
Catalytic chlorination
"Based on what evidence? More potent than the Cl2 you are forming it from?"
HUH? Can' ...
17-11-2003 at 05:52
by: Theoretic
Ni from coins
"An interesting approach to a study of the stabillity of molten NH4NO3 in the presence of heavy ...
17-11-2003 at 05:20
by: Theoretic
Benzene synthesis
My chemistry book says: 3C2H2 (Ni, 70C) =>C6H6. That's not much, but at least Ni is an activ ...
16-11-2003 at 08:48
by: Theoretic
Ni from coins
You could dissolve the coins in molten NH4NO3, heat untill all of the residual AN decomposes, then h ...
16-11-2003 at 08:46
by: Theoretic
Catalytic chlorination
Thanks for redirection! Although...
"The NCl3 generated will collect at the bottom of the reac ...
16-11-2003 at 08:30
by: Theoretic
Ethylene explorations
Very nice :D, but...
"600 ml dimethylformamide"... "extract with ether several times ...
16-11-2003 at 08:12
by: Theoretic
Garage Experiments With Trichloromethane.
Well, what can I say? NULL AND VOID. A failure. I've done it at home, my dad wouldn't let ...
16-11-2003 at 07:52
by: Theoretic
Catalytic chlorination
What do you think of catalytic chlorination,
with ammonium salts being the catalyst?
1)NH4+ + 3Cl2 ...
12-11-2003 at 09:15
by: Theoretic
Ethylene explorations
The HNO2 + alcohols actually produces an equilibrium, COULD be useful. Alcohols + (NO)2SO4 (nitrosyl ...
12-11-2003 at 08:51
by: Theoretic
Chloropicrin and its Odor
I do think that by reacting alkali with chloropicrin, you get trichloronitronates - especially as ch ...
12-11-2003 at 07:33
by: Theoretic
Ethylene explorations
Well, you are right, and it's not only for the would-be organic synthesist that CaSO4 sludges a ...
11-11-2003 at 08:34
by: Theoretic
Garage Experiments With Trichloromethane.
I was once flicking through a book - a dictionary of science and technology. In the section for chlo ...
11-11-2003 at 07:52
by: Theoretic
HNO3????
So, anyway, I think the white fumes were fumes of H2O2/concentrated NH3 solution/whatever - the heat ...
10-11-2003 at 09:13
by: Theoretic
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