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methylene iodide
From your mentioning of a 'soda bottle' I asume you are refering to [url=http://www.erowid.org/archi ...
27-4-2006 at 09:34
by: Nicodem
Chloromethylation vs. formylation
The chloromethyl group is moderately ring deactivating by inductive effect so there is little or no ...
18-4-2006 at 11:18
by: Nicodem
Chloromethylation vs. formylation
SecretSquirrel, please read the reply from Turd where he already told you that what he has is not a ...
17-4-2006 at 11:03
by: Nicodem
Condensation with Nitromethane
He is asking about making the 1-(3-acetoxyphenyl)-2-nitroethanol and not the nitrostyrene (this woul ...
16-4-2006 at 09:39
by: Nicodem
phenylalanine and carboxylic acid reduction
2-amino-3-phenylpropanoyl chloride does not exists for obvious reasons. Its hydrochloride salt is pr ...
7-4-2006 at 03:30
by: Nicodem
3-phenyl-1,1,1-triflouroacetone
Substituting the alpha-methyl group with the trifluoromethyl abolishes amphetamine-like activity in ...
1-4-2006 at 12:59
by: Nicodem
Recovery of acetaldehyde
Can't you just liquify the acetaldehyde&NOx mixture, throw it in some icy aqueous solution of so ...
27-3-2006 at 10:42
by: Nicodem
solubility of inorganic salts in organic solvents!!
If it does not form a biphasic system then yes, usually the solubility of inorganic salts decreases ...
12-3-2006 at 08:06
by: Nicodem
Nitroketone preparation and cleavage
I searched SciFinder and Beilstein and found some relevant references.

The nucleophylic substitut ...
28-2-2006 at 11:19
by: Nicodem
i,i dimethyl iodobenzene
Methyl groups are not electronegative enough to keep iodine in the +3 oxidation state.

Therefore ...
22-2-2006 at 10:32
by: Nicodem
DTBE
Correct spelling makes a big difference:
[url=http://www.google.com/search?hl=en&q=%22di-t-buty ...
22-2-2006 at 10:24
by: Nicodem
pyrrolidinediethyl diacetate?
The reaction is obviously an intramolecular Claisen condensation followed by hydrolysis/decarboxylat ...
18-2-2006 at 23:46
by: Nicodem
New FTP
In FileZilla "Site manager" dialogue click "Advanced settings" for the FTP connection settings and m ...
15-2-2006 at 13:10
by: Nicodem
Question on making CH3NO2?
Rogue chemist that is certainly a good idea to prepare nitroacetone this way. I have been thinking o ...
5-2-2006 at 03:19
by: Nicodem
Question on making CH3NO2?
There is no theoretic base for such a reaction as the formation of sodium chloroacetate from chloroa ...
4-2-2006 at 01:35
by: Nicodem
different halogens and the subsituion
Madancrazy, 1-flouro-3-bromo-5-chlorocyclooctane is not commercially available in if you are trying ...
1-2-2006 at 12:03
by: Nicodem
Nitration of Propenylbenzenes
[quote]This procedure looks extremely interesting if other people can get it to work. [/quote]

Th ...
1-2-2006 at 11:42
by: Nicodem
My version of Hexamine synthesis
Are you sure you did not over heat it while boiling it down?
You would better vacuum strip off the ...
20-1-2006 at 10:19
by: Nicodem
acetaldehyde dehydration to acetylene
The patents you refered have nothing to do with the production of acetylene from acetaldehyde. As fa ...
22-12-2005 at 15:06
by: Nicodem
isopropylamine + kmno4 then H2SO4
to acetone of course
1-12-2005 at 10:21
by: Nicodem
abnormal nitration of styrene
The nitration of styrene yields a terrible mixture of products. Depending on the conditions there so ...
29-11-2005 at 10:42
by: Nicodem
Synthesis of piperdine
[quote][i]Originally posted by sterckxke[/i]
u get piperdin-2-one
reduce that with HCl/zn é Voila ...
22-11-2005 at 11:48
by: Nicodem
Substitute glacial acetid acid with 98% acetic acid?
Well, it really is a stupid question. :P
If you are going to put 30% H2O2 together with acetic acid ...
22-11-2005 at 11:45
by: Nicodem
Toluenesulfonic acid and Sulfonic acids in genera
[quote][i]Originally posted by sparkgap[/i]
Now for my question: would removing the amine group fro ...
18-11-2005 at 10:34
by: Nicodem
Toluenesulfonic acid and Sulfonic acids in genera
The leaving group ability roughly correlates with the pKa of the originating acid (resulting anion). ...
17-11-2005 at 10:46
by: Nicodem
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