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imine reactivity ( direct carbamylation)
I don't think you'll have enough energy to cause that to tautomerize there's no use reinventing the ... |
25-5-2007 at 09:23
by: jon |
imine reactivity ( direct carbamylation)
I've never seen an example like what you propose here i don't think it will fly you can theoreticall ... |
24-5-2007 at 20:17
by: jon |
PEA and mek -> NPP?
it does'nt jibe that formalin would'nt work it goes like this the aldehyde forms the aldimine this i ... |
24-5-2007 at 10:07
by: jon |
PEA and mek -> NPP?
why do you say formaldehyde won't work from a mechanistic point of view?
[Edited on 24-5-2007 by jo ... |
24-5-2007 at 09:42
by: jon |
PEA and mek -> NPP?
nice going I went the library no luck did'nt have beilsteins abstracts nothing. |
22-5-2007 at 11:58
by: jon |
Nitrostyrene to phenyl-nitro-propanol with formaldehyde
yeah i was thinking about the ppa scheme too and it would yeild a 1,3 diol compound the scheme i thi ... |
22-5-2007 at 08:39
by: jon |
Nitrostyrene to phenyl-nitro-propanol with formaldehyde
I concluded that the sn2 reaction was the only feasible route to nitroethane the other methods are'n ... |
21-5-2007 at 21:52
by: jon |
Nitrostyrene to phenyl-nitro-propanol with formaldehyde
it seems like your working harder just to avoid working hard.
sure nitroethane is a pain but so is ... |
21-5-2007 at 18:36
by: jon |
Nitrostyrene to phenyl-nitro-propanol with formaldehyde
I just noticed that too on reading the articles sounded promising but when you dig deeper not really |
21-5-2007 at 13:43
by: jon |
PEA and mek -> NPP?
how did they arrive at 2,6 substituted products? the non-enoliziable carbonyl should make the iminiu ... |
21-5-2007 at 13:41
by: jon |
Nitrostyrene to phenyl-nitro-propanol with formaldehyde
very intersting approach! |
21-5-2007 at 10:11
by: jon |
PEA and mek -> NPP?
yeah i was looking for the same thing there's a J.A.C.S. article on it somewhere don't know where th ... |
20-5-2007 at 16:59
by: jon |
ephedrine>pcc>wolff-kishner = ?
I've seen a wolf kishner reference on ephedrine itself it seems to work because Of tautomerisn of th ... |
18-5-2007 at 10:36
by: jon |
Amino alcohol via Akabori, trial run
yes it's got a lot of useful information in it, you can go to downloads.com (c-net) and get claro "s ... |
17-5-2007 at 14:05
by: jon |
1-methyl-1,4-dihydropyridine
question? how do you get access to beilstein online? |
4-5-2007 at 09:00
by: jon |
Problem with monomethylation of amines.....
paraformaldehyde depolymerizes more easily in bases, IIRC.
I would depolymerize seperately, titurat ... |
26-4-2007 at 17:04
by: jon |
Amino alcohol via Akabori, trial run
does'nt bitter almond oil contain triglycerides as well, meaning you would have to purify it to get ... |
24-4-2007 at 13:37
by: jon |
Yes You Can Make Your Own TCT - If You Dare!
what about using the sodium salt instead to prepare the cyanogen it seems safer to me, I know it can ... |
16-4-2007 at 20:23
by: jon |
Hydrolysis of ASA
a throwback to the old utfse huh? |
14-4-2007 at 23:48
by: jon |
Amino alcohol via Akabori, trial run
man you really go out to left field on this, did you ever do a tlc chromatogram of your dmso expirim ... |
14-4-2007 at 16:54
by: jon |
washes and extractions
In general has anyone noticed what kind of structual moieties cause an amine hydrochloride to partit ... |
5-4-2007 at 21:04
by: jon |
washes and extractions
I think the amine he's refering to is teriary so it's salts would be somewhat soluble in a chlorinat ... |
1-4-2007 at 14:17
by: jon |
Need help with prep. of phthalic anhydride from naphthalene
yes anthranilic acid is watched because it is precursor to acetylanthranilic acid which is the prec ... |
25-3-2007 at 21:38
by: jon |
Need help with prep. of phthalic anhydride from naphthalene
lueko indigo looks like two indole rings fused together with a hydroxy group on each ring, you can g ... |
24-3-2007 at 15:09
by: jon |
Need help with prep. of phthalic anhydride from naphthalene
little off topic but alkali hydrolysis of leuko indigo seems to be the easiest route to anthranilic ... |
23-3-2007 at 16:55
by: jon |
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