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P4O10 and P4S10 w/Oxalyl Chloride
Complain to Gmelin not to me.

Gmelin is the inorganic Bible (even more than Mellor.)

It is the ...
29-9-2007 at 03:06
by: Sauron
P4O10 and P4S10 w/Oxalyl Chloride
Here's a relatively clear-cut reaction of P4S10 with an ortho-ester, specifically triethyl orthoform ...
29-9-2007 at 01:45
by: Sauron
adapting a domestic MW
There is an excellent article in the Recent Journal Articles of Interest section, on the best choice ...
28-9-2007 at 22:25
by: Sauron
newbies
Don't be thinking too much. Introspection will give you such a headache.

You were never the equiv ...
28-9-2007 at 21:26
by: Sauron
Phenyldichlorophosphine, Useful Reagent
Maybe there is some method of recovering the POCl3 from the AlCl3-POCl3 solid complex. That would ce ...
28-9-2007 at 21:01
by: Sauron
dumbshit question of the week - reversed ester
Try that paper I cited, third post from the top.

Anytime where the carboxyl moiety is in the 4- ...
28-9-2007 at 20:09
by: Sauron
P4O10 and P4S10 w/Oxalyl Chloride
RedP with Br5 can give either PBr3 or PBr5 depending on proportions. Normally you would make these i ...
28-9-2007 at 11:06
by: Sauron
P4O10 and P4S10 w/Oxalyl Chloride
Well normally you make a triester with all three R the same, and if all goes well and you use tertia ...
28-9-2007 at 10:45
by: Sauron
P4O10 and P4S10 w/Oxalyl Chloride
Sorry, but it's just not that simple.

You were dealing with ionic NaBr, while PBr3 is covalent P- ...
28-9-2007 at 10:10
by: Sauron
P4O10 and P4S10 w/Oxalyl Chloride
What makes you think, Mardec, that Cl2 will displace Br in PBr3?

I am all ears.

I purchase my ...
28-9-2007 at 08:39
by: Sauron
P4O10 and P4S10 w/Oxalyl Chloride
The literature contains an example of the use of phenyldichlorophosphine to reduce the complex Me[PC ...
27-9-2007 at 23:23
by: Sauron
dumbshit question of the week - reversed ester
Reversed is not the same as stereochemically inverted. For one thing a reversed ester may be achiral ...
27-9-2007 at 22:18
by: Sauron
Phenyldichlorophosphine, Useful Reagent
PhPCl2 is a trivalent phosphorus compound that is commercially available and also amenable to prepar ...
27-9-2007 at 21:56
by: Sauron
Live chat
What's next?

Nude webcams?
27-9-2007 at 17:36
by: Sauron
P4O10 and P4S10 w/Oxalyl Chloride
Another reaction of P4O10 and P4S10

Phosphorus pentoxide reacts with benzene at 275-325 C (stirr ...
27-9-2007 at 07:39
by: Sauron
Isopropanol ->[Oxidizer in question]-> Acetone
If he wants to oxidize the -OH to carbonyl with a halogen source the one to use is TCCA whi will mak ...
27-9-2007 at 01:14
by: Sauron
dumbshit question of the week - reversed ester
BERGER, ZIERING & LEE, J. org. Chem ., 1947, 12, 904

Yep, pethidine analogs, I will have the ...
27-9-2007 at 00:54
by: Sauron
Isopropanol ->[Oxidizer in question]-> Acetone
Well, I'm a little confounded by the disconnection between the thread title (2-propanol to acetone v ...
26-9-2007 at 23:46
by: Sauron
P4O10 and P4S10 w/Oxalyl Chloride
Mardec, I don't *need* PSCl2, I have a somewhat fading need for PCl3, and I am speculating that I ca ...
26-9-2007 at 19:42
by: Sauron
P4O10 and P4S10 w/Oxalyl Chloride
See Brauer for lab prep details. The nomenclature is odd, look for P2S5, or P4S10

I think he has ...
26-9-2007 at 18:57
by: Sauron
tesla electric car
M.Curie got there along with P.Curie because she was, as Stonewall Jackson puts it, "the firstest wi ...
26-9-2007 at 18:01
by: Sauron
Alexander Shulgin Books
I was reading Shulgin's papers in the primary lit. from the early 70s on. As they appeared. One Shu ...
26-9-2007 at 17:15
by: Sauron
Sartori Supplement to The War Gases
An option each must weigh for themselves, I am not to foolish as to tell someone what is or isn't ri ...
26-9-2007 at 16:57
by: Sauron
Alexander Shulgin Books
My understanding was that Sasha had a very cordial relationship with DEA up until the publication of ...
26-9-2007 at 09:57
by: Sauron
P4O10 and P4S10 w/Oxalyl Chloride
P4S10 is a solid and comes in metal cans, the ones I have are all 25 g and I have 10 of them. I will ...
26-9-2007 at 09:19
by: Sauron
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