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Experimental: Alternative to Al/Hg - the Al/Cu
In the Hyperlab post [540004] from 21. Sept. 2010, the member [i]ruzer[/i] describes what is a metho ...
2-6-2014 at 09:58
by: Nicodem
How do the reductive properties of Zinc and Zinc Amalgam differ?
[rquote=332714&tid=30450&author=FireLion3]But, if Zinc metal is a single electron donor, doe ...
30-5-2014 at 07:43
by: Nicodem
How do the reductive properties of Zinc and Zinc Amalgam differ?
[rquote=332488&tid=30450&author=FireLion3]Zinc is traditionally a two-electron reducing agen ...
28-5-2014 at 08:17
by: Nicodem
Molecular reactions database
https://www.sciencemadness.org/whisper/viewthread.php?tid=19143&goto=search&pid=246116
22-5-2014 at 11:11
by: Nicodem
Benzyl Alcohol -> Benzaldehyde via Silica Gel Supported Jones Reagent
[rquote=331890&tid=6671&author=Antiswat]Ca(ClO)2 --- consider NCl3 formation!![/rquote]
Wow ...
22-5-2014 at 11:08
by: Nicodem
Improved Synthesis of Benzyl Bromide by Free Radical Bromination
That's a relatively good purity. From the benzylic hydrogens I calculated the ratios of the four pro ...
16-5-2014 at 06:15
by: Nicodem
Rhodiums loss of GABA to GHB
[rquote=331374&tid=3159&author=Zyklonb] I added 15.4 grams of GABA (.15 mols) with 10.4 gram ...
15-5-2014 at 10:56
by: Nicodem
Benzene synthesis
[rquote=330155&tid=325&author=blogfast25]I really don't know and only go by a reference in w ...
15-5-2014 at 10:31
by: Nicodem
Improved Synthesis of Benzyl Bromide by Free Radical Bromination
Cheddite Cheese, there are a few examples of benzylic brominations with the BrO[sub]3[/sub][sup]-[/s ...
15-5-2014 at 10:02
by: Nicodem
Do stronger bases create stronger nucleophiles?
You forgot to add the reference.
Surely you don't believe anyone can answer that without knowing w ...
15-5-2014 at 05:43
by: Nicodem
Improved Synthesis of Benzyl Bromide by Free Radical Bromination
Cheddite Cheese, thank you very much for you useful contribution.
Do you have any means of checking ...
12-5-2014 at 07:27
by: Nicodem
Help with debenzylation of N-Benzyl
[rquote=330623&tid=30326&author=ChemistryAddictive]Only good sign is that balloon was shrink ...
9-5-2014 at 07:54
by: Nicodem
Do stronger bases create stronger nucleophiles?
[rquote=330611&tid=30332&author=JefferyH]If there is a compound that can be deprotonated by ...
9-5-2014 at 07:35
by: Nicodem
Help with debenzylation of N-Benzyl
[rquote=330513&tid=30326&author=ChemistryAddictive]At the moment i just have 5 % Pd/C... Now ...
8-5-2014 at 09:16
by: Nicodem
Help with debenzylation of N-Benzyl
[rquote=330501&tid=30326&author=ChemistryAddictive]I wanted to use a Transfer hydrogenation ...
8-5-2014 at 08:28
by: Nicodem
Experimental: Alternative to Al/Hg - the Al/Cu
[rquote=330333&tid=30297&author=Chemosynthesis][rquote=330329&tid=30297&author=Draco ...
7-5-2014 at 05:49
by: Nicodem
Experimental: Alternative to Al/Hg - the Al/Cu
Thank you for you contribution. Besides the reports in the long thread at the Hyperlab, I think this ...
6-5-2014 at 09:50
by: Nicodem
How stable are formaldehyde imines in aq. solutions?
Ammonia and amines do not form imines with formaldehyde. The product with ammonia is hexamine, which ...
6-5-2014 at 06:19
by: Nicodem
The Electrolytic Chlorination of Ethanol
[rquote=330168&tid=30308&author=Cheddite Cheese]I thought this reaction would produce chlora ...
6-5-2014 at 05:42
by: Nicodem
Benzyl alcohol, HCl and H2O2 strange oil?
deltaH, there was no need to ruin this thread with unsubstantiated speculations!

Antiswat, mixing ...
6-5-2014 at 05:37
by: Nicodem
Transesterification
[rquote=330010&tid=30295&author=HgDinis25][quote]
(ethanol and methanol form no azeotrope)[ ...
4-5-2014 at 10:25
by: Nicodem
Transesterification
[rquote=330006&tid=30295&author=HgDinis25]I was talking about the Nitrite all the time. Yes, ...
4-5-2014 at 07:19
by: Nicodem
Transesterification
[rquote=329999&tid=30295&author=HgDinis25]So I wondered, can the following reaction happen?
...
4-5-2014 at 06:59
by: Nicodem
One-pot arylation/acylation of primary amines
[rquote=327732&tid=30123&author=Dope Amine]Here's my thought: Use a phenylboronic acid and ...
26-4-2014 at 00:36
by: Nicodem
Scopolamine (Ester to Carboxylic acid)
Please let's not overreact and issue dramatic danger warnings to someone who is obviously too cluele ...
25-4-2014 at 23:56
by: Nicodem
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