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Hydriodic acid from iodides?
Can't we all just live in peace?
Ah, of course not, I forgot we are all humans. So I'm closing this ...
10-3-2008 at 02:34
by: Nicodem
Unknown copper compound
Aha! But "solutions" of Prussian blue are colloidal!

OK, forget about colloidal copper. Your expe ...
10-3-2008 at 00:59
by: Nicodem
www.totallysynthetic.com
[quote][i]Originally posted by MagicJigPipe[/i]
Why is it that the stereotype of a chemist looking ...
9-3-2008 at 23:58
by: Nicodem
www.totallysynthetic.com
OK, organic chemists in general are weird (I should know :( ). They are the best collection of the m ...
9-3-2008 at 11:07
by: Nicodem
Unknown copper compound
[quote][i]Originally posted by 12AX7[/i]
Cu(I) disproportionates in H2O solution. This entire thre ...
9-3-2008 at 10:21
by: Nicodem
Unknown copper compound
[quote][i]Originally posted by blogfast25[/i]
The darker colour is due to the complex of Cu+/Cu2+ o ...
9-3-2008 at 08:26
by: Nicodem
Hydroxylamine/Fremy's Salt (potassium nitrosodisulfonate) failure - help debug?
Insulting everybody in general will surely not help you in getting any reply!
If I were you I would ...
9-3-2008 at 01:16
by: Nicodem
toluene --> benzaldehyde
It only matters that the silver salt is soluble with the anion preferably inoxidable to avoid side r ...
9-3-2008 at 01:12
by: Nicodem
Synthesis of Phenylpropan-1,2-dione via acetylene?
[quote][i]Originally posted by LSD25[/i]
Lastly, which Ti(III) salts can be used? More importantly, ...
8-3-2008 at 12:34
by: Nicodem
reductive am. why inert atmosphere?
[quote][i]Originally posted by chemrox[/i]
The question is, at what point is the inert gas mandator ...
8-3-2008 at 00:42
by: Nicodem
Synthesis of 4,5-disubstituted 1,3-cyclopentanediones
Actually, what I thought was to rather start with the commercially available 1,3-cyclopentadione (ex ...
7-3-2008 at 10:14
by: Nicodem
Synthesis of 4,5-disubstituted 1,3-cyclopentanediones
I suggest looking upon some double deprotonated acetoacetate esters chemistry. There are a bunch of ...
7-3-2008 at 07:12
by: Nicodem
Possible Route to Copper Nitrate
[quote][i]Originally posted by TheApplianceOfScience[/i]
Just beware of the noxious fumes of NO2- l ...
7-3-2008 at 06:17
by: Nicodem
bromine
Standard Fluka reagent bottles (the brown ones with the famous blue stoppers) are great for storing ...
7-3-2008 at 02:52
by: Nicodem
Possible Route to Copper Nitrate
Once that I needed some copper(II) nitrate whatever hydrate I prepared it by dissolving some copper ...
7-3-2008 at 02:45
by: Nicodem
Salvinorin - finally a total synthesis
They should work now.

The discussion at the TotalySynthetic forum about the first total synthesis ...
5-3-2008 at 04:42
by: Nicodem
Biphenyl, would this method work?
Nope, that would give you benzene.

Nerro, the Kumada coupling sure can be easy when you are verse ...
5-3-2008 at 00:25
by: Nicodem
Biphenyl, would this method work?
[quote][i]Originally posted by ssdd[/i]
I have seen several references to the following reaction as ...
4-3-2008 at 11:01
by: Nicodem
diethyl malonate drevatives
Be more specific. I'm really not sure I understood what you are talking about. There is no reaction ...
3-3-2008 at 07:57
by: Nicodem
post removals
OK, there is some truth in what you say, but you are exaggerating big time. We have a "Beginnings" s ...
3-3-2008 at 07:43
by: Nicodem
"Strong" keto acid?
The pKa values for water as solvent are:

Acetone (MeCOMe) ~20
Acetylacetone ( (MeCO)<sub> ...
3-3-2008 at 04:59
by: Nicodem
Unknown copper compound
[quote][i]Originally posted by blogfast25[/i]
If I'm right that air was the problem then it shows n ...
2-3-2008 at 13:11
by: Nicodem
p-Anisidine-2-sulfonic acid
At the moment I can only come out with this alternative:
Prepare 2-amino-4-methoxy-acetanilide (ref ...
2-3-2008 at 12:56
by: Nicodem
p-Anisidine-2-sulfonic acid
It is very hard to say what and why was done just from that SciFinder output. It is very strange tha ...
2-3-2008 at 12:25
by: Nicodem
Sigma Aldrich
Welcome.
You might want to read [url=http://sciencemadness.org/talk/viewthread.php?tid=9911]this th ...
2-3-2008 at 00:10
by: Nicodem
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