Difference between revisions of "Manganese dioxide"

Revision as of 21:12, 24 August 2015

Manganese(IV) oxide

Manganese dioxide is a compound of manganese(IV) with the formula MnO₂. It is a common precursor to many manganese compounds.

Properties

Chemical

Manganese dioxide is a moderately strong oxidizing agent, and is used as such in the lab. It may be hydrated, but dehydration is easily accomplished by heating. The oxide is nonstoichiometric, with most samples being deficient in oxygen.

Physical

Manganese dioxide is a brown to black solid which is insoluble in water.

Availability

Manganese dioxide is available at pottery supply stores for only a few dollars per pound. Lab grade manganese dioxide is also available from suppliers like Elemental Scientific.

It is often pulled from D cell zinc alkaline batteries. It is easy to obtain in this way, but it is very low grade. Soluble impurities can be washed from it, but it will contain large amounts of graphite which is not easily removed. This source of MnO₂ is still useful for many applications.

Preparation

This compound is often prepared in the lab inadvertently, as a byproduct to the an oxidation by potassium permanganate, such as that of toluene:

C₆H₅CH₃ + 2KMnO₄ → 2MnO₂ + KC₆H₅COO + KOH + H₂O

It can also be prepared by adding hydrogen peroxide to potassium permanganate.

Purification from crude, battery-grade sludge was done by NurdRage by utilizing equilibria. Alternatively, it can be done by precipitating iron and manganese oxalate, then adding an excess of oxalic acid to redissolve the iron (trisoxalatoferro complex, a pale green reminiscent of Fe(II)). The insoluble manganese oxalate can then be calcined at high temperature to decent purity.

Purification of Manganese Sulfate (NurdRage)

Projects

• Preparation of manganese salts by treatment with acid. This compound will not react with some acids such as sulfuric acid, but treatment with oxalic acid with result in manganese(II) carbonate and carbon dioxide. Even more useful is its reaction with hydrochloric acid, as described below; Manganese (II) chloride and elemental chlorine are both produced and can be collected.
• Potassium permanganate synthesis
• Make elemental manganese

Handling

Safety

Manganese dioxide is a heavy metal oxide, and is reasonably toxic. Ingestion or inhalation of large amounts of manganese will cause a disease called manganism. Manganese dioxide dust is irritant to eyes and mucous tissue.

Manganese dioxide will release chlorine gas in contact with hydrochloric acid.

Manganese dioxide is an oxidizer and can react with several organic compounds.

Manganese dioxide tends to stain nearly everything it touches, especially when wet or finely divided.

Storage

Manganese dioxide is best stored in glass or plastic bottles and containers. Avoid storing the oxide in metal containers, especially steel, as it will rust the metal. Impure MnO₂ can induce corrosion in certain types of stainless steels.

Disposal

Manganese dioxide can be toxic to wildlife, so it's best to take it to disposal facilities. Since it's found in batteries, it can be taken to battery recycling centers.

References

Relevant Sciencemadness threads

• Manganese Chloride crystals