Difference between revisions of "Iron(III) oxide"
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| − | '''Iron(III) oxide''', often referred to as '''red iron oxide''', is the chemical compound with chemical formula [[iron|Fe]]<sub>2</sub>[[Oxygen|O]]<sub>3</sub>. It is the main component of rust and acts as the oxidizing agent in the classic [[thermite]] reaction with [[aluminium]]. | + | {{Chembox |
| + | | Name = Iron(III) oxide | ||
| + | | Reference = | ||
| + | | IUPACName = Iron(III) oxide | ||
| + | | PIN = | ||
| + | | SystematicName = | ||
| + | | OtherNames = Colcothar, ferric iron, ferric oxide, hematite, iron sesquioxide, maghemite, ochre, red iron oxide, rouge, rust | ||
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| + | <!-- Sections --> | ||
| + | | Section1 = {{Chembox Identifiers | ||
| + | | 3DMet = | ||
| + | | Abbreviations = | ||
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| + | }} | ||
| + | | Section2 = {{Chembox Properties | ||
| + | | AtmosphericOHRateConstant = | ||
| + | | Appearance = Red solid | ||
| + | | BoilingPt = | ||
| + | | BoilingPtC = | ||
| + | | BoilingPt_ref = | ||
| + | | BoilingPt_notes = Decomposes | ||
| + | | Density = 5.242 g/cm<sup>3</sup> | ||
| + | | Formula = Fe<sub>2</sub>O<sub>3</sub> | ||
| + | | HenryConstant = | ||
| + | | LogP = | ||
| + | | MolarMass = 159.69 g/mol | ||
| + | | MeltingPt = | ||
| + | | MeltingPtC = | ||
| + | | MeltingPt_ref = | ||
| + | | MeltingPt_notes = ''anhydrous''<br>1,539–1,565 °C (2,802–2,849 °F; 1,812–1,838 K) (decomposition)<br>''β-dihydrate''<br>105 °C (221 °F; 378 K) (decomposition)<br>''β-monohydrate''<br>150 °C (302 °F; 423 K) (decomposition)<br>''α-dihydrate''<br>50 °C (122 °F; 323 K) (decomposition)<br>''α-monohydrate''<br>92 °C (198 °F; 365 K) (decomposition) | ||
| + | | Odor = Odorless | ||
| + | | pKa = | ||
| + | | pKb = | ||
| + | | Solubility = Insoluble | ||
| + | | SolubleOther = Reacts with acids<br>Hydrates show slight solubility in [[sugar]] and mildly acidic aqueous solutions<br>Insoluble in all organic solvents | ||
| + | | Solvent = | ||
| + | | VaporPressure = | ||
| + | }} | ||
| + | | Section3 = {{Chembox Structure | ||
| + | | Coordination = Octahedral (Fe<sup>3+</sup>, α-form, β-form) | ||
| + | | CrystalStruct = [[Rhombohedral]], hR30 (α-form)<br>Cubic bixbyite, cI80 (β-form)<br>Cubic spinel (γ-form)<br>Orthorhombic (ε-form) | ||
| + | | MolShape = | ||
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| + | | Section4 = {{Chembox Thermochemistry | ||
| + | | DeltaGf = −742.2 kJ/mol | ||
| + | | DeltaHc = | ||
| + | | DeltaHf = −824.2 kJ/mol | ||
| + | | Entropy = 87.4 J·mol<sup>-1</sup>·K<sup>-1</sup> | ||
| + | | HeatCapacity = 103.9 J·mol<sup>-1</sup>·K<sup>-1</sup> | ||
| + | }} | ||
| + | | Section5 = {{Chembox Explosive | ||
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| + | | Section6 = {{Chembox Hazards | ||
| + | | AutoignitionPt = Non-flammable | ||
| + | | ExploLimits = Non-flammable | ||
| + | | ExternalMSDS = [https://www.docdroid.net/Bgnqtb5/ironiii-oxide-sa.pdf.html Sigma-Aldrich] | ||
| + | | FlashPt = Non-flammable | ||
| + | | LD50 = 10,000 mg/kg (rats, oral) | ||
| + | | LC50 = | ||
| + | | MainHazards = Irritant | ||
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| + | | Section7 = {{Chembox Related | ||
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| + | | OtherFunction = | ||
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| + | | OtherCompounds = [[Iron(II,III) oxide]] | ||
| + | }} | ||
| + | }} | ||
| + | '''Iron(III) oxide''', often referred to as '''red iron oxide''', is the chemical compound with chemical formula '''[[iron|Fe]]<sub>2</sub>[[Oxygen|O]]<sub>3</sub>'''. It is the main component of rust and acts as the oxidizing agent in the classic [[thermite]] reaction with [[aluminium]]. | ||
==Properties== | ==Properties== | ||
===Chemical=== | ===Chemical=== | ||
| − | Iron oxide is a typical metal oxide. It will react with acids to form the iron salt, so iron(III) oxide is a useful starting point to make chemicals such | + | Iron oxide is a typical metal oxide. It will react with acids to form the iron salt, so iron(III) oxide is a useful starting point to make chemicals such iron acetate. |
A mixture of red iron oxide and aluminium powders is the classic thermite mixture. This mixture, while difficult to initiate, burns in excess of 1500 °C, producing a slag of red hot molten iron and and aluminium oxide. | A mixture of red iron oxide and aluminium powders is the classic thermite mixture. This mixture, while difficult to initiate, burns in excess of 1500 °C, producing a slag of red hot molten iron and and aluminium oxide. | ||
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A quick way to whip up a lot of this oxide is reacting bulk iron (such as nails) with concentrated (60-70%) nitric acid. The reaction is very vigorous and exothermic, and the nails are quickly converted to iron (III) nitrate (and already a lot of iron (III) oxide, the liquid becomes very brown and opaque). Fuming nitric acid will react very slowly, add water carefully to start the vigorous reaction. | A quick way to whip up a lot of this oxide is reacting bulk iron (such as nails) with concentrated (60-70%) nitric acid. The reaction is very vigorous and exothermic, and the nails are quickly converted to iron (III) nitrate (and already a lot of iron (III) oxide, the liquid becomes very brown and opaque). Fuming nitric acid will react very slowly, add water carefully to start the vigorous reaction. | ||
| − | :Fe + | + | : Fe + 6 HNO<sub>3</sub>(conc) → Fe(NO<sub>3</sub>)<sub>3</sub> + NO<sub>2</sub> + 3 H<sub>2</sub>O (main reaction) |
| − | :2 Fe + | + | :2 Fe + 6 HNO<sub>3</sub> → Fe<sub>2</sub>O<sub>3</sub> + 6 NO<sub>2</sub> + 3 H<sub>2</sub>O (useful side reaction) |
| − | Add alkali, such as sodium hydroxide, to precipitate more iron (III) hydroxide, which can be calcined to yield red iron oxide. | + | Add alkali, such as sodium hydroxide, to precipitate more iron (III) hydroxide, which can be calcined to yield red iron oxide. Aqueous ammonia can also be used, as it gives better performance. |
==Projects== | ==Projects== | ||
| − | * | + | *Make [[thermite]] |
*Make elemental iron | *Make elemental iron | ||
*Ferrofluid, a "liquid magnet" | *Ferrofluid, a "liquid magnet" | ||
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==Handling== | ==Handling== | ||
===Safety=== | ===Safety=== | ||
| − | As an insoluble compound of iron, iron(III) oxide is not substantially toxic unless intentionally swallowed in larger amounts. Obviously, be wary of problems associated with tetanus. | + | As an insoluble compound of iron, iron(III) oxide is not substantially toxic unless intentionally swallowed in larger amounts. Obviously, be wary of problems associated with tetanus, mainly if your source of rust came in contact with dirt. |
| + | |||
| + | Iron(III) oxide has a tendency to stain objects, especially clothes and is a pain to remove properly. | ||
===Storage=== | ===Storage=== | ||
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<references/> | <references/> | ||
===Relevant Sciencemadness threads=== | ===Relevant Sciencemadness threads=== | ||
| + | *[http://www.sciencemadness.org/talk/viewthread.php?tid=153 Iron Oxide for use in Thermite] | ||
| + | *[http://www.sciencemadness.org/talk/viewthread.php?tid=18294 Electrolysis to make Iron (II) Hydroxide then Iron (III)Oxide?] | ||
| + | *[http://www.sciencemadness.org/talk/viewthread.php?tid=15053 Iron oxide by electrolysis] | ||
| + | *[http://www.sciencemadness.org/talk/viewthread.php?tid=14731 Iron Oxide question] | ||
| + | *[http://www.sciencemadness.org/talk/viewthread.php?tid=72687 Making Iron Oxide By Electrolysis Using Iron Nails As Electrodes] | ||
| + | *[http://www.sciencemadness.org/talk/viewthread.php?tid=21625 Electrolysis to produce red iron oxide Question] | ||
| + | *[http://www.sciencemadness.org/talk/viewthread.php?tid=3227 Color changing iron oxide] | ||
[[Category:Chemical compounds]] | [[Category:Chemical compounds]] | ||
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[[Category:Iron compounds]] | [[Category:Iron compounds]] | ||
[[Category:Oxides]] | [[Category:Oxides]] | ||
| + | [[Category:Easily prepared chemicals]] | ||
[[Category:Readily available chemicals]] | [[Category:Readily available chemicals]] | ||
[[Category:Pigments]] | [[Category:Pigments]] | ||
Latest revision as of 15:31, 26 August 2023
| Names | |
|---|---|
| IUPAC name
Iron(III) oxide
| |
| Other names
Colcothar, ferric iron, ferric oxide, hematite, iron sesquioxide, maghemite, ochre, red iron oxide, rouge, rust
| |
| Properties | |
| Fe2O3 | |
| Molar mass | 159.69 g/mol |
| Appearance | Red solid |
| Odor | Odorless |
| Density | 5.242 g/cm3 |
| Melting point | anhydrous 1,539–1,565 °C (2,802–2,849 °F; 1,812–1,838 K) (decomposition) β-dihydrate 105 °C (221 °F; 378 K) (decomposition) β-monohydrate 150 °C (302 °F; 423 K) (decomposition) α-dihydrate 50 °C (122 °F; 323 K) (decomposition) α-monohydrate 92 °C (198 °F; 365 K) (decomposition) |
| Boiling point | Decomposes |
| Insoluble | |
| Solubility | Reacts with acids Hydrates show slight solubility in sugar and mildly acidic aqueous solutions Insoluble in all organic solvents |
| Thermochemistry | |
| Std molar
entropy (S |
87.4 J·mol-1·K-1 |
| Std enthalpy of
formation (ΔfH |
−824.2 kJ/mol |
| Hazards | |
| Safety data sheet | Sigma-Aldrich |
| Flash point | Non-flammable |
| Lethal dose or concentration (LD, LC): | |
| LD50 (Median dose)
|
10,000 mg/kg (rats, oral) |
| Related compounds | |
| Related compounds
|
Iron(II,III) oxide |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Iron(III) oxide, often referred to as red iron oxide, is the chemical compound with chemical formula Fe2O3. It is the main component of rust and acts as the oxidizing agent in the classic thermite reaction with aluminium.
Contents
Properties
Chemical
Iron oxide is a typical metal oxide. It will react with acids to form the iron salt, so iron(III) oxide is a useful starting point to make chemicals such iron acetate.
A mixture of red iron oxide and aluminium powders is the classic thermite mixture. This mixture, while difficult to initiate, burns in excess of 1500 °C, producing a slag of red hot molten iron and and aluminium oxide.
Red iron oxide is sometimes added to KNO3 and sugar mixtures to help accelerate the reaction, which is needed when making 'rocket candy' rockets.
Physical
Iron(III) oxide is a deep red compound usually encountered in powdered form. It is insoluble in water but readily reacts with acids. It is noticeably ferromagnetic, accumulating thickly on the surface of magnets. While ferrofluid, a magnetic liquid suspension, is typically made with iron(II,III) oxide, the magnetic properties of iron(III) oxide may also allow for this to be made.
Availability
Sometimes used as a colouring agent for things such as concrete. Pottery supply stores will have this chemical for the same reason.
Due to the well known thermite reaction, it is commonly available in large amounts online.
Preparation
Iron can be slowly oxidized by oxygen in the presence of salt water to red iron oxide.
A more effective way to produce large amounts of iron oxide is through electrolysis. A solution of sodium chloride is electrolyzed with two iron electrodes, producing insoluble iron(II) oxide.
This is filtered out and heated until dry and then strong heating in air converts the black iron(II) oxide to the red iron(III) oxide.
A quick way to whip up a lot of this oxide is reacting bulk iron (such as nails) with concentrated (60-70%) nitric acid. The reaction is very vigorous and exothermic, and the nails are quickly converted to iron (III) nitrate (and already a lot of iron (III) oxide, the liquid becomes very brown and opaque). Fuming nitric acid will react very slowly, add water carefully to start the vigorous reaction.
- Fe + 6 HNO3(conc) → Fe(NO3)3 + NO2 + 3 H2O (main reaction)
- 2 Fe + 6 HNO3 → Fe2O3 + 6 NO2 + 3 H2O (useful side reaction)
Add alkali, such as sodium hydroxide, to precipitate more iron (III) hydroxide, which can be calcined to yield red iron oxide. Aqueous ammonia can also be used, as it gives better performance.
Projects
- Make thermite
- Make elemental iron
- Ferrofluid, a "liquid magnet"
- Make magnetite
- Make ferrates
Handling
Safety
As an insoluble compound of iron, iron(III) oxide is not substantially toxic unless intentionally swallowed in larger amounts. Obviously, be wary of problems associated with tetanus, mainly if your source of rust came in contact with dirt.
Iron(III) oxide has a tendency to stain objects, especially clothes and is a pain to remove properly.
Storage
No special storage is required, though it will stain many materials and clothing and may induce rusting in steels.
Disposal
No special disposal is required, unless is contaminated with heavy metals.
