Difference between revisions of "Miscibility"

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<u>'''THIS ARTICLE IS IN FOR A MASSIVE OVERHAUL!!! DO NOT EDIT WHILE WORK IS BEING DONE!!!'''</u>
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'''Miscibility''' is the property of substances to mix in all proportions, forming a homogeneous solution. If the two substances are soluble, but do not mix in all proportions, they are soluble, but not miscible. Although the term is most often applied to liquids, it can also be used to gases and even solids.
 
'''Miscibility''' is the property of substances to mix in all proportions, forming a homogeneous solution. If the two substances are soluble, but do not mix in all proportions, they are soluble, but not miscible. Although the term is most often applied to liquids, it can also be used to gases and even solids.
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The table below displays the miscibility of various liquids, at standard conditions (T = 20 °C, p = 1 atm). The liquids are considered pure and free of other solvents or water (expect water of course).
  
 
==Miscibility of various solvents==
 
==Miscibility of various solvents==
 
{|class="wikitable"
 
{|class="wikitable"
 
! style="text-align:center;"| Solvent
 
! style="text-align:center;"| Solvent
−
! style="width:3em;" | [[File:1,2-Dichloroethane vertical.png|link=1,2-Dichloroethane]]
+
! style="width:3em;" | [[1,2-Dichloroethane]]
−
! style="width:3em;" | [[File:1,4-Dioxane vertical.png|link=1,4-Dioxane]]
+
! style="width:3em;" | [[1,4-Dioxane]]
−
! style="width:3em;" | [[File:2,2,4-Trimethylpentane vertical.png|link=2,2,4-Trimethylpentane]]
+
! style="width:3em;" | [[2,2,4-Trimethylpentane]]
−
! style="width:3em;" | [[File:Acetaldehyde vertical.png|link=Acetaldehyde]]
+
! style="width:3em;" | [[Acetaldehyde]]
−
! style="width:3em;" | [[File:Acetic acid vertical.png|link=Acetic acid]]
+
! style="width:3em;" | [[Acetic acid]]
−
! style="width:3em;" | [[File:Acetone vertical.png|link=Acetone]]
+
! style="width:3em;" | [[Acetone]]
−
! style="width:3em;" | [[File:Acetonitrile vertical.png|link=Acetonitrile]]
+
! style="width:3em;" | [[Acetonitrile]]
−
! style="width:3em;" | [[File:Benzene vertical.png|link=Benzene]]
+
! style="width:3em;" | [[Benzene]]
−
! style="width:3em;" | [[File:Butane vertical.png|link=Butane]]
+
! style="width:3em;" | [[Butane]]
−
! style="width:3em;" | [[File:Butanol vertical.png|link=Butanol]]
+
! style="width:3em;" | [[Butanol]]
−
! style="width:3em;" | [[File:Butyl acetate vertical.png|link=Butyl acetate]]
+
! style="width:3em;" | [[Butyl acetate]]
−
! style="width:3em;" | [[File:Carbon disulfide vertical.png|link=Carbon disulfide]]
+
! style="width:3em;" | [[Carbon disulfide]]
−
! style="width:3em;" | [[File:Carbon tetrachloride vertical.png|link=Carbon tetrachloride]]
+
! style="width:3em;" | [[Carbon tetrachloride]]
−
! style="width:3em;" | [[File:Chloroform vertical.png|link=Chloroform]]
+
! style="width:3em;" | [[Chloroform]]
−
! style="width:3em;" | [[File:Cyclohexane vertical.png|link=Cyclohexane]]
+
! style="width:3em;" | [[Cyclohexane]]
−
! style="width:3em;" | [[File:Dichloromethane vertical.png|link=Dichloromethane]]
+
! style="width:3em;" | [[Dichloromethane]]
−
! style="width:3em;" | [[File:Diethyl ether vertical.png|link=Diethyl ether]]
+
! style="width:3em;" | [[Diethyl ether]]
−
! style="width:3em;" | [[File:Diisopropyl ether vertical.png|link=Diisopropyl ether]]
+
! style="width:3em;" | [[Diisopropyl ether]]
−
! style="width:3em;" | [[File:Dimethylformamide vertical.png|link=Dimethylformamide]]
+
! style="width:3em;" | [[Dimethylformamide]]
−
! style="width:3em;" | [[File:Dimethyl sulfoxide vertical.png|link=Dimethyl sulfoxide]]
+
! style="width:3em;" | [[Dimethyl sulfoxide]]
−
! style="width:3em;" | [[File:Ethanol vertical.png|link=Ethanol]]
+
! style="width:3em;" | [[Ethanol]]
−
! style="width:3em;" | [[File:Ethyl acetate vertical.png|link=Ethyl acetate]]
+
! style="width:3em;" | [[Ethyl acetate]]
−
! style="width:3em;" | [[File:Ethylene glycol vertical.png|link=Ethylene glycol]]
+
! style="width:3em;" | [[Ethylene glycol]]
−
! style="width:3em;" | [[File:Ethylenediamine vertical.png|link=Ethylenediamine]]
+
! style="width:3em;" | [[Ethylenediamine]]
−
! style="width:3em;" | [[File:Formic acid vertical.png|link=Formic acid]]
+
! style="width:3em;" | [[Formic acid]]
−
! style="width:3em;" | [[File:Glycerol vertical.png|link=Glycerol]]
+
! style="width:3em;" | [[Glycerol]]
−
! style="width:3em;" | [[File:Heptane vertical.png|link=Heptane]]
+
! style="width:3em;" | [[Heptane]]
−
! style="width:3em;" | [[File:Hexane vertical.png|link=Hexane]]
+
! style="width:3em;" | [[Hexane]]
−
! style="width:3em;" | [[File:Isopropanol vertical.png|link=Isopropanol]]
+
! style="width:3em;" | [[Isopropanol]]
−
! style="width:3em;" | [[File:Limonene vertical.png|link=Limonene]]
+
! style="width:3em;" | [[Limonene]]
−
! style="width:3em;" | [[File:Methanol vertical.png|link=Methanol]]
+
! style="width:3em;" | [[Methanol]]
−
! style="width:3em;" | [[File:Methyl ethyl ketone vertical.png|link=Methyl ethyl ketone]]
+
! style="width:3em;" | [[Methyl ethyl ketone]]
−
! style="width:3em;" | [[File:Methyl formate vertical.png|link=Methyl formate]]
+
! style="width:3em;" | [[Methyl formate]]
−
! style="width:3em;" | [[File:Methyl tert-butyl ether vertical.png|link=Methyl tert-butyl ether]]
+
! style="width:3em;" | [[Methyl tert-butyl ether]]
−
! style="width:3em;" | [[File:Nitromethane vertical.png|link=Nitromethane]]
+
! style="width:3em;" | [[Nitromethane]]
−
! style="width:3em;" | [[File:Octyl acetate vertical.png|link=Octyl acetate]]
+
! style="width:3em;" | [[Octyl acetate]]
−
! style="width:3em;" | [[File:Pentane vertical.png|link=Pentane]]
+
! style="width:3em;" | [[Pentane]]
−
! style="width:3em;" | [[File:Petroleum ether vertical.png|link=Petroleum ether]]
+
! style="width:3em;" | [[Petroleum ether]]
−
! style="width:3em;" | [[File:Propanol vertical.png|link=Propanol]]
+
! style="width:3em;" | [[Propanol]]
−
! style="width:3em;" | [[File:Propylene carbonate vertical.png|link=Propylene carbonate]]
+
! style="width:3em;" | [[Propylene carbonate]]
−
! style="width:3em;" | [[File:Propylene glycol vertical.png|link=Propylene glycol]]
+
! style="width:3em;" | [[Propylene glycol]]
−
! style="width:3em;" | [[File:Pyridine vertical.png|link=Pyridine]]
+
! style="width:3em;" | [[Pyridine]]
−
! style="width:3em;" | [[File:Schweizer's reagent vertical.png|link=Schweizer's reagent]]
+
! style="width:3em;" | [[Schweizer's reagent]]
−
! style="width:3em;" | [[File:Tetrahydrofuran vertical.png|link=Tetrahydrofuran]]
+
! style="width:3em;" | [[Tetrahydrofuran]]
−
! style="width:3em;" | [[File:Trichloroethylene vertical.png|link=Trichloroethylene]]
+
! style="width:3em;" | [[Trichloroethylene]]
−
! style="width:3em;" | [[File:Toluene vertical.png|link=Toluene]]
+
! style="width:3em;" | [[Toluene]]
−
! style="width:3em;" | [[File:Water vertical.png|link=Water]]
+
! style="width:3em;" | [[Water]]
−
! style="width:3em;" | [[File:Xylene vertical.png|link=Xylene]]
+
! style="width:3em;" | [[Xylene]]
 
|-
 
|-
 
! [[1,2-Dichloroethane]]
 
! [[1,2-Dichloroethane]]
Line 2,458: Line 2,462:
 
*[https://www.erowid.org/archive/rhodium/pdf/solvent.miscibility.pdf Solvent miscibility table]
 
*[https://www.erowid.org/archive/rhodium/pdf/solvent.miscibility.pdf Solvent miscibility table]
 
*[http://delloyd.50megs.com/moreinfo/immiscible.html Immiscible solvents]
 
*[http://delloyd.50megs.com/moreinfo/immiscible.html Immiscible solvents]
 +
*[https://pubs.acs.org/doi/abs/10.1021/ie50515a065 Miscibility of Organic Solvent Pairs, J. S. Drury, Ind. Eng. Chem., 1952, 44 (11), pp 2744–2744]
 +
*[https://pubs.acs.org/doi/abs/10.1021/ie50600a039 Miscibility of Organic Solvent Pairs, W. M. Jackson, and J. S. Drury, Ind. Eng. Chem., 1959, 51 (12), pp 1491–1493]
 +
*[https://books.google.ro/books?id=J9iCsCN83wsC&pg=PA524&lpg=PA524&dq=solubility+of+nitroglycerin+in+solvents&source=bl&ots=4SRmn84Fxy&sig=d1HWQ89FHgHarpAqBDly0PQj9n8&hl=ro&sa=X&ved=0ahUKEwj8ufbTprXaAhXEbFAKHcJJAKQQ6AEIUzAG#v=onepage&q=solubility%20of%20nitroglycerin%20in%20solvents&f=false Analytical Profiles of Drug Substances, Klaus Florey, Vol 9, pag. 524]
  
 
[[Category:Chemical properties]]
 
[[Category:Chemical properties]]
 
[[Category:Data tables]]
 
[[Category:Data tables]]

Latest revision as of 18:51, 12 April 2018

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THIS ARTICLE IS IN FOR A MASSIVE OVERHAUL!!! DO NOT EDIT WHILE WORK IS BEING DONE!!!

Miscibility is the property of substances to mix in all proportions, forming a homogeneous solution. If the two substances are soluble, but do not mix in all proportions, they are soluble, but not miscible. Although the term is most often applied to liquids, it can also be used to gases and even solids.

The table below displays the miscibility of various liquids, at standard conditions (T = 20 °C, p = 1 atm). The liquids are considered pure and free of other solvents or water (expect water of course).

Miscibility of various solvents

Solvent 1,2-Dichloroethane 1,4-Dioxane 2,2,4-Trimethylpentane Acetaldehyde Acetic acid Acetone Acetonitrile Benzene Butane Butanol Butyl acetate Carbon disulfide Carbon tetrachloride Chloroform Cyclohexane Dichloromethane Diethyl ether Diisopropyl ether Dimethylformamide Dimethyl sulfoxide Ethanol Ethyl acetate Ethylene glycol Ethylenediamine Formic acid Glycerol Heptane Hexane Isopropanol Limonene Methanol Methyl ethyl ketone Methyl formate Methyl tert-butyl ether Nitromethane Octyl acetate Pentane Petroleum ether Propanol Propylene carbonate Propylene glycol Pyridine Schweizer's reagent Tetrahydrofuran Trichloroethylene Toluene Water Xylene
1,2-Dichloroethane
1,4-Dioxane
2,2,4-Trimethylpentane
Acetaldehyde
Acetic acid
Acetone
Acetonitrile
Benzene
Butane
Butanol
Butyl acetate
Carbon disulfide
Carbon tetrachloride
Chloroform
Cyclohexane
Dichloromethane
Diethyl ether
Diisopropyl ether
Dimethylformamide
Dimethyl sulfoxide
Ethanol
Ethyl acetate
Ethylene glycol
Ethylenediamine
Formic acid
Glycerol
Heptane
Hexane
Isopropanol
Limonene
Methanol
Methyl ethyl ketone
Methyl formate
Methyl tert-butyl ether
Nitromethane
Octyl acetate
Pentane
Petroleum ether
Propanol
Propylene carbonate
Propylene glycol
Pyridine
Schweizer's reagent
Tetrahydrofuran
Trichloroethylene
Toluene
Water
Xylene

References

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