Difference between revisions of "Hypophosphorous acid"
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Latest revision as of 21:59, 14 June 2020
| Names | |
|---|---|
| IUPAC name
Phosphinic acid
| |
| Other names
Hydroxy(oxo)-λ5-phosphane
Hydroxy-λ5-phosphanone Oxo-λ5-phosphanol Oxo-λ5-phosphinous acid | |
| Properties | |
| H3PO2 HOP(O)H2 | |
| Molar mass | 66.00 g/mol |
| Appearance | Colorless, deliquescent crystals or oily liquid |
| Odor | Odorless |
| Density | 1.493 g/cm3 1.22 g/cm3 (50 wt% aq. solution) |
| Melting point | 26.5 °C (79.7 °F; 299.6 K) |
| Boiling point | 130 °C (266 °F; 403 K) (decomposes) |
| Miscible | |
| Solubility | Very soluble in alcohols, diethyl ether |
| Vapor pressure | ~0 mmHg |
| Acidity (pKa) | 1.2 |
| Hazards | |
| Safety data sheet | Sigma-Aldrich (50%) |
| Flash point | Non-flammable |
| Related compounds | |
| Related compounds
|
Phosphine |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Hypophosphorous acid (HPA) or phosphinic acid, is a phosphorus oxyacid and a powerful reducing agent with molecular formula H3PO2. The formula for this acid is generally written H3PO2, but a more descriptive presentation is HOP(O)H2, which highlights its monoprotic character. HPA sometimes exists in equilibrium with the minor tautomer HP(OH)2.
Contents
Properties
Chemical
Hypophosphorous acid can reduce chromium(III) oxide to chromium(II) oxide:
- H3PO2 + 2 Cr2O3 → 4 CrO + H3PO4
Physical
Hypophosphorous acid is a colorless, deliquescent solid at standard conditions, that readily melts above 26.5 °C and due to its strong hygroscopicity, it cannot be solidified again without decomposition in open air.
Availability
It is sold by chemical suppliers, as 50% aq. solution.
Because hypophosphorous acid can reduce elemental iodine to form hydroiodic acid, which is a reagent effective for reducing ephedrine or pseudoephedrine to methamphetamine, the United States Drug Enforcement Administration designated hypophosphorous acid (and its salts) as a List I precursor chemical and thus cannot be acquired by the hobby chemist.
Preparation
White phosphorus is carefully added to hot aqueous solution of an alkaline hydroxide, like NaOH or even Ca(OH)2. This produces hypophosphite salts.
- P4 + 4 OH− + 4 H2O → 4 H
2PO−
2 + 2 H2
The hypophosphite salt is then treated with a strong, non-oxidizing acid to give the free hypophosphorous acid:
- H
2PO−
2 + H+ → HOP(O)H2
Anhydrous acid cannot be obtained by simple evaporation of the water, as the acid ready oxidizes to phosphorous acid and phosphoric acid, as well as disproportionates to phosphorous acid and phosphine.
Pure anhydrous hypophosphorous acid however, can be obtained by the continuous extraction of its aqueous solution with diethyl ether.
Projects
- Reducing agent
- Reduction of arenediazonium salts to arenes
- Make chromium(II) oxide
- Make metal complexes
- Electroless nickel plating
Handling
Safety
HPA is a mid-strength acid, irritant and corrosive. Reduction may generate phosphine, which is very toxic and flammable.
Storage
In air-tight plastic bottles, away from light and oxidizers.
Disposal
Should be oxidized to phosphoric acid by careful oxidation in aq. solution. Diluted hydrogen peroxide can be used for this task.
