Difference between revisions of "Magnesium sulfate"
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| − | + | {{Chembox | |
| − | + | | Name = Magnesium sulfate | |
| − | '''Magnesium sulfate''', commonly known as '''Epsom salt''', is the inorganic compound with chemical formula [[Magnesium|Mg]][[Sulfate|SO<sub>4</sub>]], the [[magnesium]] salt of [[sulfuric acid]]. Commonly referred to in its hydrated form by the name Epsom Salt, magnesium sulfate is one of the cheapest and most easily obtained lab chemicals. Its anhydrous form finds use as a desiccant and it is also a somewhat useful reagent in aqueous double replacement reactions. | + | | Reference = |
| + | | IUPACName = Magnesium sulfate | ||
| + | | PIN = | ||
| + | | SystematicName = | ||
| + | | OtherNames = English salt<br>Bitter salts<br>Bath salts<br>Epsom salt<br>Epsomite | ||
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| + | | ImageFile1 = Mgso4.JPG | ||
| + | | ImageSize1 = 250 | ||
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| + | | ImageCaption1 = Magnesium sulfate heptahydrate monocrystal (Epsom Salt) | ||
| + | | ImageFile2 = Anhydrous magnesium sulfate.jpg | ||
| + | | ImageSize2 = 250 | ||
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| + | | ImageCaption2 = Anhydrous magnesium sulfate, a popular desiccant | ||
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| + | <!-- Sections --> | ||
| + | | Section1 = {{Chembox Identifiers | ||
| + | | 3DMet = | ||
| + | | Abbreviations = | ||
| + | | SMILES = | ||
| + | }} | ||
| + | | Section2 = {{Chembox Properties | ||
| + | | AtmosphericOHRateConstant = | ||
| + | | Appearance = White solid | ||
| + | | BoilingPt = | ||
| + | | BoilingPtC = | ||
| + | | BoilingPt_ref = | ||
| + | | BoilingPt_notes = | ||
| + | | Density = 2.66 g/cm<sup>3</sup> (anhydrous)<br>2.445 g/cm<sup>3</sup> (monohydrate)<br>1.68 g/cm<sup>3</sup> (heptahydrate)<br>1.512 g/cm<sup>3</sup> (undecahydrate) | ||
| + | | Formula = MgSO<sub>4</sub> | ||
| + | | HenryConstant = | ||
| + | | LogP = | ||
| + | | MolarMass = 120.366 g/mol (anhydrous)<br>138.38 g/mol (monohydrate)<br>174.41 g/mol (trihydrate)<br>210.44 g/mol (pentahydrate)<br>228.46 g/mol (hexahydrate)<br>246.47 g/mol (heptahydrate) | ||
| + | | MeltingPt = | ||
| + | | MeltingPtC = | ||
| + | | MeltingPt_ref = | ||
| + | | MeltingPt_notes = ''anhydrous''<br>1,124 °C (2,055 °F; 1,397 K) (decomposes)<hr>''monohydrate''<br>200 °C (392 °F; 473 K) (decomposes)<hr>''heptahydrate''<br>150 °C (302 °F; 423 K) (decomposes)<hr>''undecahydrate''<br>2 °C (36 °F; 275 K) (decomposes) | ||
| + | | Odor = Odorless | ||
| + | | pKa = | ||
| + | | pKb = | ||
| + | | Solubility = ''anhydrous''<br> 26.9 g/100 ml (0 °C)<br>35.1 g/100 ml (20 °C)<br>50.2 g/100 ml (100 °C)<hr>''heptahydrate''<br>71 g/100 ml (20 °C) | ||
| + | | SolubleOther = Slightly soluble in [[alcohol]], [[glycerol]] <br>Insoluble in [[acetone]], [[benzene]], [[toluene]] | ||
| + | | Solubility1 = 1.16 g/100 ml (18 °C) | ||
| + | | Solvent1 = diethyl ether | ||
| + | | VaporPressure = ~0 mmHg | ||
| + | }} | ||
| + | | Section3 = {{Chembox Structure | ||
| + | | Coordination = | ||
| + | | CrystalStruct = Monoclinic (hydrate) | ||
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| + | | Section4 = {{Chembox Thermochemistry | ||
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| + | | Section5 = {{Chembox Explosive | ||
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| + | | DetonationV = | ||
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| + | }} | ||
| + | | Section6 = {{Chembox Hazards | ||
| + | | AutoignitionPt = Non-flammable | ||
| + | | ExploLimits = Non-explosive | ||
| + | | ExternalMSDS = [https://www.docdroid.net/O382rIm/magnesium-sulfate-anhydrous-sa.pdf.html Sigma-Aldrich] (anhydrous) | ||
| + | | FlashPt = Non-flammable | ||
| + | | LD50 = | ||
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| + | | OtherAnions = | ||
| + | | OtherCations = | ||
| + | | OtherFunction = | ||
| + | | OtherFunction_label = | ||
| + | | OtherCompounds = [[Calcium sulfate]]<br>[[Strontium sulfate]]<br>[[Barium sulfate]] | ||
| + | }} | ||
| + | }} | ||
| + | '''Magnesium sulfate''', commonly known as '''Epsom salt''', is the inorganic compound with chemical formula '''[[Magnesium|Mg]][[Sulfate|SO<sub>4</sub>]]''', the [[magnesium]] salt of [[sulfuric acid]]. Commonly referred to in its hydrated form by the name Epsom Salt, magnesium sulfate is one of the cheapest and most easily obtained lab chemicals. Its anhydrous form finds use as a desiccant and it is also a somewhat useful reagent in aqueous double replacement reactions. | ||
==Properties== | ==Properties== | ||
===Chemical=== | ===Chemical=== | ||
| − | Magnesium sulfate is readily very soluble in water, while [[magnesium carbonate]] and [[magnesium hydroxide|hydroxide]] are not, allowing it to be a simple way to produce either by addition to an alkali metal carbonate or hydroxide. These two chemicals are useful in producing other magnesium salts. It can also be used as a way to add sulfate ions to a solution, such as to create [[calcium sulfate]] from [[calcium | + | Magnesium sulfate is readily very soluble in water, while [[magnesium carbonate]] and [[magnesium hydroxide|hydroxide]] are not, allowing it to be a simple way to produce either by addition to an alkali metal carbonate or hydroxide. |
| + | |||
| + | : MgSO<sub>4</sub> + Na<sub>2</sub>CO<sub>3</sub> → MgCO<sub>3</sub> + Na<sub>2</sub>SO<sub>4</sub> | ||
| + | |||
| + | These two chemicals are useful in producing other magnesium salts. It can also be used as a way to add sulfate ions to a solution, such as to create [[calcium sulfate]] from [[calcium chloride]]. | ||
| + | |||
| + | Finally, it can be used as an electrolyte during [[electrolysis]] to produce soluble sulfates in situ. | ||
===Physical=== | ===Physical=== | ||
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* Electrolysis of water | * Electrolysis of water | ||
* Growing crystals | * Growing crystals | ||
| + | |||
==Handling== | ==Handling== | ||
===Safety=== | ===Safety=== | ||
| Line 25: | Line 142: | ||
===Storage=== | ===Storage=== | ||
| − | + | Magnesium sulfate should be kept in closed bottles or bags. The anhydrous form should be stored in sealed containers. | |
===Disposal=== | ===Disposal=== | ||
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===Relevant Sciencemadness threads=== | ===Relevant Sciencemadness threads=== | ||
*[http://www.sciencemadness.org/talk/viewthread.php?tid=21108 Drying of Magnesium Sulfate] | *[http://www.sciencemadness.org/talk/viewthread.php?tid=21108 Drying of Magnesium Sulfate] | ||
| + | *[http://www.sciencemadness.org/talk/viewthread.php?tid=54920 Best Way to Dry MgSO4] | ||
| + | *[http://www.sciencemadness.org/talk/viewthread.php?tid=9429 Dehydrating MgSO4 completely????] | ||
| + | *[http://www.sciencemadness.org/talk/viewthread.php?tid=62656 drying with MgSO4] | ||
| + | *[http://www.sciencemadness.org/talk/viewthread.php?tid=13978 MgSO4 decomposition] | ||
| + | *[http://www.sciencemadness.org/talk/viewthread.php?tid=64103 Magnesium Sulfate] | ||
*[http://www.sciencemadness.org/talk/viewthread.php?tid=16097 Magnesium Sulfate thermite] | *[http://www.sciencemadness.org/talk/viewthread.php?tid=16097 Magnesium Sulfate thermite] | ||
*[http://www.sciencemadness.org/talk/viewthread.php?tid=61656 Magnesium sulfate as a substitute for Calcium Gluconate in dealing with HF?] | *[http://www.sciencemadness.org/talk/viewthread.php?tid=61656 Magnesium sulfate as a substitute for Calcium Gluconate in dealing with HF?] | ||
| + | *[http://www.sciencemadness.org/talk/viewthread.php?tid=7444 Epsom Salts] | ||
[[Category:Chemical compounds]] | [[Category:Chemical compounds]] | ||
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[[Category:Sulfates]] | [[Category:Sulfates]] | ||
[[Category:Magnesium compounds]] | [[Category:Magnesium compounds]] | ||
| + | [[Category:Neutral salts]] | ||
[[Category:Desiccants]] | [[Category:Desiccants]] | ||
| − | |||
| − | |||
[[Category:Chemicals for crystal growing]] | [[Category:Chemicals for crystal growing]] | ||
| − | |||
[[Category:Solids]] | [[Category:Solids]] | ||
| + | [[Category:Readily available chemicals]] | ||
| + | [[Category:Materials available as food grade]] | ||
| + | [[Category:Essential reagents]] | ||
| + | [[Category:Irritants]] | ||
Latest revision as of 12:03, 17 February 2019
 Magnesium sulfate heptahydrate monocrystal (Epsom Salt)
| |
 Anhydrous magnesium sulfate, a popular desiccant
| |
| Names | |
|---|---|
| IUPAC name
Magnesium sulfate
| |
| Other names
English salt
Bitter salts Bath salts Epsom salt Epsomite | |
| Properties | |
| MgSO4 | |
| Molar mass | 120.366 g/mol (anhydrous) 138.38 g/mol (monohydrate) 174.41 g/mol (trihydrate) 210.44 g/mol (pentahydrate) 228.46 g/mol (hexahydrate) 246.47 g/mol (heptahydrate) |
| Appearance | White solid |
| Odor | Odorless |
| Density | 2.66 g/cm3 (anhydrous) 2.445 g/cm3 (monohydrate) 1.68 g/cm3 (heptahydrate) 1.512 g/cm3 (undecahydrate) |
| Melting point | anhydrous 1,124 °C (2,055 °F; 1,397 K) (decomposes) monohydrate 200 °C (392 °F; 473 K) (decomposes) heptahydrate 150 °C (302 °F; 423 K) (decomposes) undecahydrate 2 °C (36 °F; 275 K) (decomposes) |
| anhydrous 26.9 g/100 ml (0 °C) 35.1 g/100 ml (20 °C) 50.2 g/100 ml (100 °C) heptahydrate 71 g/100 ml (20 °C) | |
| Solubility | Slightly soluble in alcohol, glycerol Insoluble in acetone, benzene, toluene |
| Solubility in diethyl ether | 1.16 g/100 ml (18 °C) |
| Vapor pressure | ~0 mmHg |
| Hazards | |
| Safety data sheet | Sigma-Aldrich (anhydrous) |
| Flash point | Non-flammable |
| Related compounds | |
| Related compounds
|
Calcium sulfate Strontium sulfate Barium sulfate |
| Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Magnesium sulfate, commonly known as Epsom salt, is the inorganic compound with chemical formula MgSO4, the magnesium salt of sulfuric acid. Commonly referred to in its hydrated form by the name Epsom Salt, magnesium sulfate is one of the cheapest and most easily obtained lab chemicals. Its anhydrous form finds use as a desiccant and it is also a somewhat useful reagent in aqueous double replacement reactions.
Contents
Properties
Chemical
Magnesium sulfate is readily very soluble in water, while magnesium carbonate and hydroxide are not, allowing it to be a simple way to produce either by addition to an alkali metal carbonate or hydroxide.
- MgSO4 + Na2CO3 → MgCO3 + Na2SO4
These two chemicals are useful in producing other magnesium salts. It can also be used as a way to add sulfate ions to a solution, such as to create calcium sulfate from calcium chloride.
Finally, it can be used as an electrolyte during electrolysis to produce soluble sulfates in situ.
Physical
Magnesium sulfate is most commonly encountered when purchased as the heptahydrate, usually called Epsom Salt. Solutions of magnesium sulfate easily yield well-formed transparent crystals on evaporation. At 200°C these crystals lose water to yield the anhydrous magnesium sulfate, which is very hygroscopic and as such is frequently used as a desiccant to dry organic solvents.
Availability
Most if not all pharmacies, department, and grocery stores carry Epsom salt, the heptahydrate of magnesium sulfate. Veterinary pharmacies also sell Epsom salt. A typical consumer price is about one dollar per pound in the United States, making it very cheap.
Preparation
While impractical given the extreme ease to obtain magnesium sulfate, it can be created by the action of sulfuric acid on the carbonate, hydroxide, or oxide of magnesium as well as magnesium metal itself.
Projects
- Dry your own solvents
- Electrolysis of water
- Growing crystals
Handling
Safety
Magnesium sulfate is of very low toxicity, and is often used both topically and internally in medicine. Ingesting large amounts, however, may cause the magnesium sulfate to fulfill its duty as a saline laxative, possibly causing dehydration. It will also supply the oxygen-hungry gut flora with an overabundance of sulfate ion, which they will happily reduce to sulfide, rendering the consumer's flatulence eye-watering.
Storage
Magnesium sulfate should be kept in closed bottles or bags. The anhydrous form should be stored in sealed containers.
Disposal
Magnesium sulfate can be safely poured down the drain or in the ground.
